Jacques Buffle is Professor Emeritus of analytical and environmental chemistry. He joined the staff of the Department of Inorganic, Analytical and Applied Chemistry of the University of Geneva, Switzerland, in the late sixties. Amongst many other cooperations, he has been also an Invited Professor at INRS-Eau, University of Quebec, Canada, for 20 years and Associate Professor of Electroanalytical Chemistry at the University of Lausanne, Switzerland. He was a member of the Division committee of IUPAC Division of Chemistry and the Environment, and a member of the Research Council of the Swiss National Foundation, from 1992 to 2000. He has authored about 260 research publications, 2 books, and is a co-editor of 5 other monographs. He is Series co-editor with H.P. van Leeuwen, of the IUPAC Series on Analytical and Physical Chemistry of Environmental Systems. He teached under- and postgraduate courses in analytical and environmental chemistry.
His research interests are the relationships between structure and Functionning of aquatic environmental compartments (water, sediments, soils). This includes in particular the understanding of the physicochemical processes and microstructures regulating the circulation of chemical compounds in aquatic environmental compartments (water, sediment, soils), the roles of these processes on biota and the development of in situ sensors and integrated analytical systems for the measurement of the corresponding key physico-chemical parameters. He is particularly interested in contributing to the understanding of macroscale effects, at the level of whole soils, lakes etc.., by microscale phenomena, at the molecular, colloidal and microbial level, by considering multidisciplinary approaches.

J. BUFFLE - PUBLICATIONS

MONOGRAPHS

14. J. Buffle Complexation reactions in aquatic systems. An analytical approach (700 pp)
Ellis Horwood Pub., Chichester (1988)

13. D. Monnier, W. Haerdi, J. Buffle, Y. Rusconi Chimie analytique. Application aux
méthodes instrumentales, radiochimiques et à la chimie de l'environnement (280 pp) Georg. Pub., Genève (1979)

Scientific Editor of monographs:

12. N. Senesi, K.J. Wilkinson, (Eds) (J. Buffle, H.P. van Leeuwen, Series Editors)
Biophysical Chemistry of Fractal Structures and Processes in Environmental Systems
Vol. 11, IUPAC Series in Analytical and Physical Chemistry of Environmental Systems.
Wiley, Chichester (2008)

11. K.J. Wilkinson, J.R. Lead, /Eds) (J. Buffle, H.P. van Leeuwen, Series Editors)
Environmental colloids and particles. Behaviour, Separation and Characterization..
IUPAC Series in Analytical and Physical Chemistry of Environmental Systems. Wiley,
Chichester (2007)

10. H.P. van Leeuwen, W. Köster /Eds) (J. Buffle, H.P. van Leeuwen, Series Editors)
Physico-chemical kinetics and transport at biointerfaces. IUPAC Series in Analytical and
Physical Chemistry of Environmental Systems. Wiley, Chichester (2004)

9. P.M. Huang, J-M. Bollag, N. Senesi (Eds) (J. Buffle, H.P. van Leeuwen, Series Editors)
Interactions between soil particles and microorganisms. Impact on the terrestrial
ecosystem. IUPAC Series in Analytical and Physical Chemistry of Environmental
Systems. Wiley, Chichester (2002)

8. D.R. Turner, K.A. Hunter (Eds) (J. Buffle, H.P. van Leeuwen, Series Editors) The
biogeochemistry of iron in sea water. Vol 7. IUPAC Series in Analytical and Physical
Chemistry of Environmental Systems. Wiley, Chichester (2001)

7. J. Buffle, G. Horvai (Eds) (J. Buffle, H.P. van Leeuwen, Series Editors) In situ
Monitoring of Aquatic Systems,Vol. 6 IUPAC Series in Analytical and Physical
Chemistry of Environmental Systems. Wiley, Chichester (2000)

6. R. Harrison, R. van Grieken, Eds (J. Buffle, H.P. van Leeuwen, Series Editors)
Atmospheric particles, Vol.5, IUPAC Environmental Analytical and Physical Chemistry
Series, Wiley Pub. Chichester, UK (1998)

5. P.M. Huang, N. Senesi, J. Buffle, Eds (J. Buffle, H.P. van Leeuwen, Series
Editors)Structure and surface reactions of soil particles Vol.4, IUPAC Environmental
Analytical and Physical Chemistry Series, Wiley Pub. Chichester, UK (1998)

4. A. Tessier, D. Turner, Eds (J. Buffle, H.P. van Leeuwen, Series Editors Metal speciation
and bioavailability in aquatic systems; Vol. 3, IUPAC Environmental Analytical and
Physical Chemistry Series, Wiley Pub, Chichester, UK (1995)

3. J. Buffle, R. De Vitre (Eds) Chemical and biological regulation of aquatic systems.
Lewis Pub.(1994)

2. J. Buffle, H.P. van Leeuwen (Eds) Environmental particles. Vol. 2; IUPAC
Environmental Analytical Chemistry Series; Lewis Pub., Chelsea, MI (1993)

1. J. Buffle, H.P. van Leeuwen (Eds) Environmental particles. Vol. 1; IUPAC
Environmental Analytical Chemistry Series; Lewis Pub., Chelsea, MI (1992)

CHAPTERS OF MONOGRAPHS

28. N. Fatin-Rouge, J. Buffle Study of environmental systems by means of fluorescence
correlation spectroscopy Chap. 10 in Environmental Colloids, Vol. 11 (J. Lead, K.
Wilkinson, Eds); ); IUPAC Series in Analytical and Physical Chemistry of
Environmental Systems (J. Buffle, HP van Leeuwen, Series Eds), Wiley (2007)

27. G.G. Leppard, and J. Buffle. Colloids and dissolved organics: Role in membrane and
depth filtration. pp. 99-103 In: Water Encyclopedia, Volume 2: Water Quality and
Resource Development. J.H. Lehr & J. Keeley eds. Wiley-Interscience, Hoboken, NJ,
USA (2005).

26. M. Filella, J. Buffle, N. Parthasarathy Humic and fulvic compounds , in Encyclopedia of
Analytical Science, Vol 4, p. 288-298, 2nd Ed., P.J. Worsfold , A. Townshend, C.F.
Pool (Eds) Elsevier, Oxford (2005)

25. K. Wilkinson, J. Buffle Critical Evaluation of physico-chemical parameters and
processes for modelling the biological uptake of trace metals in environmental (aquatic)
systems. Chap. 10, in Physico-chemical kinetics and transport at chemical
biological interphases. Vol. 9. (HP van Leeuwen, W. Koestler, Eds); IUPAC Series
in Analytical and Physical Chemistry of Environmental Systems (J. Buffle, HP van
Leeuwen, Series Eds), Wiley (2004)

24. M-L Tercier-Waeber, J. Buffle Microcapteurs et sondes voltammetriques pour la
mesure in situ des éléments traces dans les milieux aquatiques. Chap. 11, in
Microcapteurs chimiques et biologiques ; Applications en milieu liquide, Tome 2,
P. Fabry, J. Fouletier (Eds) Hermes Science Publication, Paris (2003)

23. R.M. Town, H. Emons, J. Buffle Speciation Analysis by Electrochemical Methods.
Chap. 5.9 in Handbook of Environmental Speciation: Techniques and
Methodology. R. Cornelis, H. Crews, J. Caruso, K. Heumann (EDS, J. Wiley (2003)

22. M. Filella, R.M. Town, J. Buffle Speciation in fresh waters, p.188-236, in Chemical
Speciation in the Environment, 2nd edition, (A.M. Ure, C.M. Davidson, Eds) ,
Blackwell Science, Oxford (2002)

21. N. Parthasarathy, P.Salaun, M. Pelletier, J. Buffle Permeation liquid membrane coupled
to voltammetric detection for in situ trace metal speciation studies. p. 102-124, in
Environmental Electrochemistry: Analysis of Trace Element Biogeochemistry.
(M. Taillefert, T.F. Rozan , Eds), ACS Symposium Series n° 811, Washington DC
(2002)

20. ML Tercier-Waeber, J. Buffle, M. Koudelka-Hep, F. Graziottin Submersible voltammetric probes for in situ real-time trace element monitoring in natural aquatic systems. Ch. 2, in Environmental Electrochemistry: Analysis of Trace Element Biogeochemistry. (M. Taillefert, T.F. Rozan , Eds), ACS Symposium Series n° 811, Washington DC (2002)

19. K. Startchev, K. Wilkinson, J. Buffle Application of FCS to the study of environmental
systems in: Fluorescence Correlation Spectroscopy. Theory and ApplicationR.
Rigler, E.L. Elson (Eds), Springer-Verlag, p. 2242-2254 (2002)

18. J. Buffle, N. Parthasarathy, N.-K. Djane, L. Matthiasson Permeation Liquid Membranes
for Field Analysis and Speciation of Trace Compounds in Waters chap. 10 in In situ
monitoring of aquatic systems; Chemical analysis and speciation IUPAC Series in
Analytical and Physical Chemistry of Environmental Systems. Wiley, Chichester
(2000)

17. J. Buffle, M.L. Tercier In situ voltammetry: concepts and practice for trace analysis
and speciation chap. 9, p. 279-405 in In situ monitoring of aquatic systems;
Chemical analysis and speciation IUPAC Series in Analytical and Physical Chemistry
of EnvironmentalSystems. Wiley, Chichester (2000)

16. J. Buffle, G. Horvai General Concepts p. 1-17 in:
In Situ Monitoring of Aquatic Systems: Chemical Analysis and SpeciationJ. Buffle and G. Horvai (Eds), John Wiley & Sons Ltd (2000)

15. M. Filella, J. Buffle Colloids in: Encyclopedia of Geochemistry, C.P. Marshall, R.W.
Fairbridge (Eds), Kluwer Academic Publ., p. 98-99 (1999)

14. G.G. Leppard and J. Buffle Aquatic Colloids and Macromolecules; Effect on analytical
results in Encyclopedia of Environmental Analysis and Remediation
J. Wiley and Sons 349-377 (1998)

13. N. Parthasarathy, M. Filella, J. Buffle Measurement of complexation properties of
metal ions in biological systems by ultrafiltration in Handbook of metal-ligand
interactions in biological fluids, Vol. 2 (G. Berthon, ed.) (1996)

12. J. Buffle, M. Filella What is environmental chemistry in Global Environmental
Change Science: Education and Training (D.J. Waddington, Ed.), Nato ASI Series,
Springer, Berlin (1995)

11. D. Perret, Gary G. Leppard, J. Buffle Environmental applications
Encyclopedia of Analytical Science, p. 3222-3228, Academic Press, London (1995)

10. M. Filella, R. Town, J. Buffle Speciation in fresh waters, chap. 7 in Chemical
Speciation in the Environment (A.M. Ure and C.M. Davidson Eds), Blackie
Academic & Professional, London (1995)

9. J. Buffle, M. Filella, R.S. Altmann Polyfunctional description of metal complexation by
natural organic matter OECD Document S.301-12, Proceedings of an NEA
Workshop, Bad Zurzach(CH) (1994); Pub: OECD, Paris (1995)

8. J. Buffle, D. Perret, M. Newman The use of filtration and ultrafiltration for size
fractionation of aquatic particles, colloids and macromolecules, in Characterization of
Environmental Particles, Vol. 1; IUPAC Environmental Analytical Chemistry Series; J.
Buffle, H.P. van Leeuwen (Eds), Lewis Pub., Michigan (1992)

7. D. Perret, R.R. DeVitre, G.G. Leppard, J. Buffle Autochtonous iron particles and
colloids in lakes, or the need to develop particle analysis methods. ch. 12 in Large
Lakes: Ecological Structure and Function M.M. Tilzer, C. Serruya (Eds), Springer-
Verlag, Berlin (1990)

6. J. Buffle The ecological role of aquatic organic and inorganic components, deduced
from their nature, circulation and interactions. in Metal Speciation in the
Environment. Series of the NATO Advanced Study Institute. J.A.C. Broeckaert, S.
Guçer, F. Adams (Eds), Springer-Verlag, Berlin (1989)

5. J. Buffle, R.R. DeVitre, D. Perret Combining field measurements for speciation in non
perturbable water samples, ch. 5 in Metal speciation: theory analysis, applications
J.R. Kramer, H.E. Allen (Eds) Lewis Pub. Inc., Michigan (1988)

4. J. Buffle, R.S. Altmann Interpretation of metal complexation by heterogeneous
complexants. ch. 13, in Aquatic surface chemistry,W. Stumm (Ed) Wiley-Interscience,
N.Y. (1987)

3. J. Buffle, O. Zali, J. Zumstein, R.R. DeVitre, W. Haerdi Combining analytical methods
for direct measurement of speciation. Application to seasonnal changes of iron, sulfur
and pedogenic and aquagenic organic constituents in a productive lake. in Reviews in
Analytical Chemistry. Euroanalysis VA. Hulanicki (Ed), Akademiai Kiado Pub.,
Budapest (1986)

2. J. Buffle Natural organic matter and metal-organic interactions in aquatic systems, p.
165-221, ch. 6 in Metal ions in biological systems, Vol. 18: Circulation of metals in
the environment H. Sigel (Ed), M. Dekker Inc., N.Y. (1984)

1. J. Buffle, A. Tessier, W. Haerdi Interpretation of trace metal complexation by aquatic
organic matter, p. 301-316, in Complexation of Trace Metals in Natural Waters
C.J.M. Kramer, J.C. Duinker (Eds)Martinus Nijhoff/Dr. W. Junk Pubs., The Hague
(1984)

SCIENTIFIC PAPERS PUBLISHED IN PEER-REVIEWED JOURNALS

232. Braungardt C.B., Achterberg E.P.*, Axelsson B., Buffle J., Graziottin F., Howell K.A., Illuminati S., Scarponi G., Tappin A.D., Tercier-Waeber M.-L., Turner D. Analysis of dissolved metal fractions in coastal waters : An intercomparison of five voltammetric in situ profiling (VIP) systems. Mar. Chem. 114 47-55 (2009).

231. J. Buffle, K.W. Wilkinson, H.P. van Leeuwen
Chemodynamics and bioavailability in natural waters
Env. Sci. Technol. 43 7170-7174 (2009)

230. H.P. van Leeuwen, J. Buffle
Chemodynamics of aquatic metal complexes: from small ligands to colloids
Env. Sci. Technol. 43 7175-7183 (2009)

229. Z. Zhang, J. Buffle
Interfacial metal flux in ligand mixtures. Part III Unexpected flux enhancement due to
kinetic interplay at the consuming surface, computed for aquatic systems
Env. Sci. Technol. 43 5762-5768 (2009)

228. S. Bayen, P. Gunkel-Grillon, I. Worms, M. Martin, J. Buffle
Influence of inorganic complexes on the transport of trace metals through permeation
liquid membranes
Anal. Chim. Acta 646 104-110 (2009)

227. Z. Zhang, J. Buffle, R. Town, J. Puy, H. P. van Leeuwen
Interfacial metal flux in ligand mixtures. Part II Flux enhancement due to kinetic
interplay : comparison of the reaction layer approximation with a rigorous approach
J. Phys. Chem. A 113 6572-6580 (2009)

226. Z. Zhang, J. Buffle
Interfacial metal flux in ligand mixtures. Part I. The revisited reaction layer
approximation: theory and examples of applications.
J. Phys. Chem. A 113 6562-6571 (2009)

225. M. Seijo, S. Ulrich, M. Filella, J. Buffle, S. Stoll
Modeling the adsorption and coagulation of fulvic acids on colloids by brownian
dynamic simulations.
Env. Sci. Technol. 43 7265-7269 (2009)

224. S. Bayen, J. Buffle
Hollow-fiber liquid-phase microextraction of polychlorinated biphenyls: dynamic
aspects and analytical challenges associated with their speciation.
J. Int. Env. Anal. Chem. 89 277-292 (2009)

223. S. Bayen, TL. Ter Laak, J. Buffle, J. Hermens
Dynamic exposure of organisms and passive samplers to hydrophobic chemicals
Env. Sci. Technol. 43 2206-2215 (2009)

222. Z. Zhang, J. Buffle
Metal flux and dynamic speciation at (bio)interfaces. Part VI: The roles of simple,
fulvic and aggregate complexes on metal flux in freshwater ligand mixtures:
comparison of Pb, Zn and Ni at planar and microspherical interfaces
Geochim. Cosmochim. Acta 73 1236-1246 (2009)

221. Z. Zhang, J. Buffle
Metal flux and dynamic speciation at (bio)interfaces. Part V: The roles of simple, fulvic
and aggregate complexes on Pb flux in freshwater ligand mixtures, computed at planar
consuming interfaces.
Geochim. Cosmochim. Acta 73 1223-1235 (2009)

220. K. Wojciechowski, M. Kucharek, J. Buffle
Mechanism of Cu(II) Transport Through Permeation Liquid Membranes Using
Azacrown Ether and Fatty Acid as Carrier"
J. Membr. Sci. 314, 152-162 (2008)

219. M. Seijo, S. Ulrich, M. Filella, J. Buffle, S. Stoll
Modeling the surface charge evolution of spherical nanoparticles by considering dielectric discontinuity effects at the solid/electrolyte solution interface
J. Coll. Int. Sci. 322 660-668 (2008)

218. S. Bayen, M-L. Tercier-Waeber, N. Parthasarathy, J. Buffle.
Highlights of analytical chemistry in Switzerland - analytical concepts and tools for
speciation studies.
Chimia 62, 170 (2008)

217. Z. Zhang, J. Buffle, K.Startchev, D. Alemani
FLUXY : a simple code for computing steady-state metal fluxes at consuming
(bio)interfaces, in natural waters.
Env. Chem. 5 204-217 (2008)

216. P. Gunkel, J. Buffle
Speciation of Cu(II) with a Flow-through Permeation Liquid Membrane:
discrimination between free copper, labile and inert Cu(II) complexes under natural
water conditions.
The Analyst 132 954-961 (2008)

215. N. Parthasarathy, M. Pelletier, J. Buffle
Transport of lipophilic ligands through permeation liquid membrane in relation to
natural water analysis
J. Memb. Sci. 309 182-188 (2008)

214. D. Alemani, J. Buffle, Z. Zhang, J. Galceran, B. Chopard
Metal flux and dynamic speciation at (bio)interfaces). Part IV. MHEDYN, a general
code for metal flux computation; application to particulate complexants and their
mixturse with the other natural ligands.
Env. Sci. Tech. 42 2028-2033 (2008)

213. D. Alemani, J. Buffle, Z. Zhang, J. Galceran, B. Chopard
Metal flux and dynamic speciation at (bio)interfaces). Part III. MHEDYN, a general
code for metal flux computation; application to simple and fulvic complexants.
Env. Sci. Tech. 42 2021-2027 (2008)

212. M-L. Tercier-Waeber, F. Confalonieri, M. Koudelka-Hep, J. Dessureault-Rompré,
F.Graziottin, J. Buffle Gel-integrated voltammetric microsensors and submersible
probes as reliable tools for environmental trace metal analysis and speciation
Electroanalysis, 20 240-258 (2008)

211. K. Wojciechowski, J. Buffle, R. Miller
Kinetics of Adsorption of Azacrown Ether and Fatty Acid at the Toluene-Water
Interface in the Presence of Metal Ions,
Coll. Surf. A, 298, 63-71 (2007)

210. Z. Zhang, J. Buffle, D. Alemani Metal flux and dynamic speciation at (bio)interfaces.
Part II: Evaluation and compilation of physico-chemical parameters for complexes with
particles and aggregates.
Env. Sci. Technol, 41 7621-7631 (2007)

209. J. Buffle, Z. Zhang, K. Startchev Metal flux and dynamic speciation at (bio)interfaces.
Part I: Critical evaluation and compilation of physico-chemical parameters for
complexes with simple ligands and fulvic substances.
Env. Sci. Technol, 41, 7609-7620 (2007)

208. D. Alemani, B. Chopard, J. Galceran, J. Buffle Study of three grid refinement methods in
the Lattice-Boltzmann framework, for reactive-diffusive processes.
International J. of Modern Physics C 18 722-731 (2007)

207. J. Buffle, K.Startchev, J. Galceran Steady-state metal flux at microorganisms and
bioanalytical sensor interfaces in multiligand systems. The reaction layer
approximation and its comparison with exact solution.
Phys. Chem. Chem. Phys. 9 2844-2855 (2007)

206. Z. Zhang, J. Buffle, H.P. van Leeuwen Role of dynamic metal speciation and membrane
permeability in metal flux through lipophilic membranes. General theory and
experimental validation with non labile complexes
. Langmuir 23 5216-5226 (2007)

205. J. Labille J., N. Fatin-Rouge, J. Buffle Local and average Diffusion of Nanosolutes in
Agarose Gel: the Effect of the Gel/Solution Interphase Structure
Langmuir 23 2083-2090 (2007)

204. H.P. van Leeuwen, R.M.Town, J. Buffle Impact of ligand protonation on Eigen-type
metal complexation kinetics in aqueous Systems
J. Phys. Chem. A, 111 2115-2121 (2007)

203. S. Bayen, K.J. Wilkinson, J. Buffle The permeation liquid membrane as a sensor for
free nickel in aqueous samples
The analyst 132 262-267 (2007)

202. S. Bayen, I. Worms, N. Parthasarathy, J. Buffle, K.J. Wilkinson Cadmium
bioavailability and speciation, using the permeation liquid membrane.
Anal. Chim. Acta 575 267-273 (2006)

201. M. Seijo, S. Ulrich, M. Filella, J. Buffle, S. Stoll Effects of surface site distribution and
dielectric discontinuity on the charging behavior of nanoparticles. A Grand Canonical
Monte Carlo study. Phys. Chem. Chem. Phys. 8 5679-5688 (2006).

200. S. Noel, M-L. Tercier-Waeber, L. Lin, J. Buffle, O. Guénat, M. Koudelka-Hep
Integrated microelectroanalytical system for direct simultaneous voltammetric
measurements of free meta ion concentrations in natural waters
Electroanalysis 18 2061-2069 (2006)

199. D. Alemani, B. Chopard, J. Galceran, J. Buffle Two grid refinement methods in the
Lattice-Boltzmann framework for reaction-diffusion processes in complex systems
Phys. Chem. Chem. Phys. 8 4119 - 4131 (2006)

198. S. Noel, J. Buffle, N. Fatin-Rouge, J. Labille Factors affecting the flux of
macromolecular, labile, metal complexes at consumable interfaces in water and inside
agarose gel. SSCP study and environmental implications
J. Electroanal. Chem. 595 125- 135 (2006)

197. Z. Zhang , J. Buffle, H.P. van Leeuwen, K. Wojciechowski Role of metal ion
complexation and membrane permeability on the metal flux through lipophilic
membranes. Labile complexes at Permeation Liquid Membran.
Analytical Chemistry 78 5693- 5703 (2006)

196. N. Fatin-Rouge, K. Wilkinson, K. Startchev, J. Kohlbrecher , J. Buffle Combining small
angle neutron scattering (SANS) to fluorescence correlation spectroscopy (FCS)
measurements to relate diffusion in agarose gel to structure.l
J. Phys. Chem. B 110 20133 - 20142 (2006)

195. D. Alemani, B. Chopard, J. Galceran, J. Buffle Time splitting and grid refinement
methods in the Lattice Boltzmann framework for solving a reaction-diffusion process. International Conference on Computational Science (ICCS) 2006 ,
Proceedings, Part II, Lecture Notes in Computer Science Vol. 3992 pp. 70-77
Alexandrov V.N., van Albada, G.D.; Sloot, P.M.A.; Dongarra, J.J.
(Eds.) XXXV, Springer-Verlag, Berlin (2006)

194. J.F.L. Duval, V.I. Slaveykova, M. Hosse, J. Buffle, K.J. Wilkinson Electrodynamic
properties of succinoglycan as probed by fluorescence correlation spectroscopy,
potentiometric titration, and capillary electrophoresis.
Biomacromolecules 7 2818-2826 (2006)

193. J.F.L. Duval, J. Buffle, H.P. van Leeuwen Quasi-reversible faradaic depolarization
processes in the electrokinetics of the metal/solution interface
J. Phys. Che. B 110 6081-6094 (2006)

192. A. Laguecir, S. Ulrich, J. Labille, N. Fatin-Rouge, S. Stoll, J. Buffle Size and pH effect
on electrical and conformational behaviour of a poly-acrylic acid: simulation and
experiments
European Polymer Journal 42 1135-1144 (2006)

191. Emily R. Unsworth, Kent W. Warnken, Hao Zhang, William Davison, Frank Black,
Jacques Buffle, Jun Cao, Rob Cleven, Josep Galceran, Peggy Gunkel, Erwin Kalis,
David Kistler, Herman P. van Leeuwen, Michel Martin, Stéphane Noël, Yusuf Nur,
Niksa Odzak, Jaume Puy, Willem van Riemsdijk, Laura Sigg, Erwin Temminghoff,
Mary-Lou Tercier-Waeber, Stefanie Toepperwien, Raewyn M. Town, Liping Weng, and
Hanbin Xue Model Predictions of Metal Speciation in Freshwaters Compared to
Measurements by In Situ Techniques
Env. Sci. Technol. 40 1942-1949 (2006)

190. Laura Sigg, Frank Black, Jacques Buffle, Jun Cao, Rob Cleven, William Davison, Josep
Galceran, Peggy Gunkel, Erwin Kalis, David Kistler, Michel Martin, Stéphane Noël,
Yusuf Nur, Niksa Odzak, Jaume Puy, Willem van Riemsdijk, Erwin Temminghoff,
Mary-Lou Tercier-Waeber, Stefanie Toepperwien, Raewyn M. Town, Emily Unsworth,
Kent W. Warnken, Liping Weng, Hanbin Xue, and Hao Zhang Comparison of
Analytical Techniques for Dynamic Trace Metal Speciation in Natural Freshwaters
Env, Sci. Technol. 40 1934-1941 (2006)

189. A. Porquet, J. Duval, J. Buffle Random computer generation of 3D molecular
structures: Theoretical and statistical analysis
Macromolecules. Theory and Simulation 15 147-162 (2006)

188. Wojciechowski K., Buffle J., Miller R. The synergistic adsorption of fatty acid and
azacrownether at the toluene-water interface.
Colloids and Surf. A. 261 49-55 (2005)

187. H.P. van Leeuwen, R.M. Town, J. Buffle, R.F.M.J. Cleven, W. Dawison, J. Puy, W.H.
van Riemsdijk, L. Sigg Dynamic speciation analysis, and bioavailability of metals in
aquatic systems.
Env. Sc. Iechnol. 39 8545 - 8556 (2005)

186. D. Alemani, B. Chopard, J. Galceran, J. Buffle LBGK method coupled to time-splitting
technique for solving reaction-diffusion processes in complex systems
Phys. Chem. Chem. Phys. 7 3331-3341 (2005)

185. J.F.L. Duval, K. Wilkinson, H.P. van Leeuwen, J. Buffle Humic substances are not hard
spheres: permeability determinations from electrophoretic mobility measurements
Env. Sci. Technol. 39 6435- 6445 (2005)

184. M-L Tercier-Waeber, F. Confalonieri, G. Riccardi, A Sina, S. Noel, J. Buffle, F.
Graziottin Multi physical-chemical profiler for real time in situ monitoring of trace
metal speciation and master variables. Development, validation and field applications
Marine Chemistry 97 216-235 (2005)

183. J. Buffle, M-L Tercier-Waeber Voltammetric environmental trace metal analysis and
speciation. From laboratory to in situ measurements
Trends in Anal Chem. 24 172-191 (2005)

182. Wojciechowski K., Buffle J. The interaction of azacrown ether with faty acid in non
polar solvents and at the organic-aqueous interface
Biosensors and bioelectronics 20 1051-59 (2004)

181. Slaveykova V. I., Parthasarathy N., Buffle J., Wilkinson K.J. Permcation liquid
membrane as a tool for monitoring bioavailable Pb in natural waters
Sci. Tot. Env. 328 55-68 (2004)

180. Fatin-Rouge N., Startchev K., Buffle J. Size effects on diffusion processes within
Agarose gels
Biophysical J. 86 2710-2719 (2004)

179. Salaün P., Josserand J., Girault H.H., J. Morandini and Buffle J. Numerical simulations
of linear scan anodic stripping voltammetry at a modified square array of
hemispherical microelectrodes located in a thin-layer cell.
J. Electroanal. Chem. 566 147-158 (2004)

178. Salaün P. and Buffle J. Integrated microanalytical system coupling Permeation Liquid
membrane and voltammetric detection for trace metal speciation. Theory and
applications.
Anal. Chem., 76 31-39 (2004)

177. Salaün P., Berdondini L., Bujard F., Koudelka-Hep M. and Buffle J. Integrated
microanalytical system coupling Permeation Liquid Membrane and Voltammetry for
Trace Metal Speciation. Technical description and Optimisation.
Electroanalysis, 16 811-820 (2004)

176. Parthasarathy N., Pelletier M., Buffle J. Permeation liquid membrane for trace metal
speciation in natural waters: transport of liposoluble Cu(II) complexes.
J. Chromatography A 1025, 33-40 (2004)

175. N.Parthasarathy, M. Pelletier, J. Buffle The use of Permeation Liquid Membrane as an
analytical tool for trace metal speciation studies in natural waters
J. Phys. IV France 107 1021-1024 (2003)

174. S. Noel, M-L. Tercier-Waeber, L. Lin, J. Buffle Complexing gel integrated
microelectrode array for direct detection of free metal ion concentrations in natural
waters
J. Phys. IV France 107 965-968 (2003)

173. Fatin-Rouge N., Milon A., Buffle J., Goulet R., Tessier A. Diffusion and Partitioning of
Solutes in Agarose Hydrogel: Relative Importance of Electrostatic and Specific
Interactions
J. Phys. Chem. B, 107, 12126-12137 (2003)

172. Salaün P., Guenat O., Berdondini L., Buffle J., Koudelka-Hep M. Voltammetric
Microsystems for trace elements monitoring
Anal. Lett., 36 (9), 1835-1849 (2003)

171. Ferreti R., Stoll S., Zhang J., Buffle J. Flocculation of hematite particles by
comparatively large polysaccharide, the Schizophyllan
J. Coll. Int. Science., 266, 328-338 (2003)

170. Tomaszewski L., Buffle J., Galceran J. Theoretical and Analytical Characterization of a
Flow-throug Permeation Liquid Membrane with controlled Flux for metal Speciation
Measurements
Anal.Chem., 75 (4), 893-900 (2003)

169. Ueberfeld J., Parthasarathy N., Zbinden H., Gisin N., Buffle J. Coupling Fiber Optics to
a Permeation Liquid Membrane for Heavy Metal Sensor Development
Anal. Chem. 74 664-670 (2002)

168. Leng X., Startchev K., Buffle J. Adsorption of fluorescent dyes on oxide nanoparticles,
studied by Fluorescence Correlation Spectroscopy
Langmuir, 18, 7602 (2002)

167. Leng X., Startchev K., Buffle J. Application of fluorescence correlation spectroscopy: a
study of flocculation of rigid rod-like biopolymer (Schyzophyllan) and colloidal article.
J. Coll. Int. Sci., 251, 64-72 (2002)

166. Wilkinson, K.J., A. Reinhardt, S. Stoll and J. Buffle Determining some of the role(s) of
natural organic matter based upon its physicochemical structure Proceedings of the 4th
conference of the French IHSS (International Humic Substances Society), France and
GRUTTE (Groupement de recherche universitaire sur les techniques de traitement et
d'épuration des eaux). pp. 2-8 (2001).

165. Knauer K., Buffle J. Adsorption of fulvic acid on algal surface and its effects on carbon
Uptake
J. Phycol., 37, 4751 (2001)

164. Stoll S., Starchev K., Wilkinson K., Chodanowski P., Balnois E., Leng X., Buffle J. The
study of environmental biopolymers by mathematical modelling and single molecular
detection techniques
Chimia, 55, 190-195 (2001)

163. Parthasarathy N., Pelletier M., Tercier-Waeber M.L., Buffle J. On-Line coupling of flow-
through voltammetric microcell to hollow fiber permeation liquid membrane device for
subnanomolar trace metal speciation measurements
Electroanalysis, 13, 1305-1314 (2001)

162. Leng X., Starchev K., Buffle J. Application of Fluorescence Correlation Spectroscopy.
Measurement of size-mass relationship of native and denaturated
Schizophyllan
Biopolymers, 59, 290-299 (2001)

161. Starchev K., Ricka J., Buffle J. Noise on Fluorescence Correlation Spectroscopy
Journal of Colloid and Interface Science 233, 50-55 (2001)

160. Pei J., Tercier-Waeber M.L., Buffle J., Fiaccabrino G.C., Koudelka-Hep M. Individually
addressable gel-integrated voltammetric microelectrode array for high resolution
measurements of concentration profiles at interfaces
Anal. Chem., 73, 2273-2281 (2001)

159. Guyon F., Parthasarathy N., Buffle J. Permeation Liquid Membrane Metal Transport :
Studies of Complex Stoechiometries and Reactions in Cu(II) Extraction with the Mixture
22DD-laurate in Toluene/Phenylhexane
Anal. Chem.., 72, 1328-1333, 2000

158. Hosse M., Lead J.R., Wilkinson K., Buffle J. Structural characterization of aquatic
biopolymers by capillary electrophoresis.Proceedings of the Symposium on Refractory
Organic Substances in the Environment, Karlsruhe (1-3/8/2000)

157. Eric Balnois, Serge Stoll, Kevin J. Wilkinson and Jacques Buffle Conformations of
Succinoglycan As Observed by Atomic Force Microscopy
Macromolecules, 33, 7440-7447 (2000)

156. M.-L. Tercier-Waeber et J. Buffle Submersible online oxygen removel system coupled to
an in situ voltammetric probe for trace element monitoring in freshwater
Environ.Sci.&Technol., 34, 18, 4018-4024 (2000)

155. S.E.J. Buykx, M.A.G.T. van den Hoop, R.F.M.J. Cleven, J. Buffle and K. J. Wilkinson
Particles in natural surface waters: chemical composition and size distribution
Intern.J. Environ.Anal.Chem., 77(1), 75-93 (2000)

154. J. R. Lead, K. J. Wilkinson, K. Startchev, S. Canonica and J. Buffle Determination of
diffusion coefficients of humic substances by fluorescence correlation spectroscopy:
role of solution conditions
Environ.Sci.Technol., 34, 1365-1369 (2000)

153. M. Filella, H. van Leeuwen, J. Buffle et K. Holub Voltammetry of chemically
heterogeneous metal complex systems. Part II. Simulation of the kinetic effects induced
on polarographic waves
J.Electroanal.Chem., 485,144-153 (2000)

152. J. Pei, X. Li, J. Buffle Preparation, characterization and application of an electrode
modified with electropolymerized CuPtBr6 film
Electrochimica Acat, 45, 1581-1593 (2000)

151. O.C. Keller, J. Buffle Voltammetric and reference microelectrodes with integrated
microchannels for flow through voltammetry. Part II. Coupling the microcell to a SLM
preconcentration technique.
Anal.Chem. 72,5, 943-948 (2000)

150. O. C. Keller, J. Buffle Voltammetric and reference microelectrodes with integrated
microchannels for flow through voltammetry. Part I. The microcell.
Anal.Chem., 72,5, 936-942 (2000)
149. M.-L. Tercier-Waeber, J. Pei, J. Buffle, G.C. Fiaccabrino, M. Koudelka-Hep, G.Riccardi,
F. Confalonieri, A. Sina, F. Graziottin A novel voltammetric probe with individually
addressable gel-integrated microsensor arrays for real-time high spatial resolution
concentration profile measurements . Electroanalysis, 12 27-34 (2000)

148. J. Pei, M.-L. Tercier-Waeber, J. Buffle Simultaneous determination and speciation of
zinc, cadmium, lead and copper in natural water with minimum handling and artefacts,
by voltammetry on gel-integrated microelectrode array
Anal.Chem., 72, 161-171 (2000)

147. E. Balnois, K.J. Wilkinson, J.R. Lead, J. Buffle Atomic force microscopy of humic
substances: effects of pH and ionic strength
Env.Sci.Technol., 33, 3911-3917 (1999)

146. M.-L. Tercier-Waeber, J. Buffle, F. Confalonieri, G. Riccardi, A. Sina, F.
Graziottin,G.C. , Fiaccabrino, M. Koudelka-Hep Submersible voltammetric probes for in-situ real-time trace element measurements in surface water, groundwater and sediment-water interface
Meas.Sci.Technol. 10, 1202-1213 (1999)

145. K.J. Wilkinson, E. Balnois, G.G. Leppard, J. Buffle Characteristic features of the major
components of freshwater colloidal organic matter revealed by transmission electron and
atomic force microscopy
Colloids and Surfaces 155, 287-310 (1999)

144. K. Starchev, J. Buffle, E. Pérez Applications of Fluorescence Correlation Spectroscopy:
Polydispersity Measurements
Journal of Colloid and Interface Science, 213, 479-487 (1999)

143.N. Parthasarathy, J. Buffle, N. Gassama, F. Cuenod Speciation of trace metals in
waters: direct selective separation and preconcentration of free metal ion by supported liquid membrane
Chemia Analityczna (Warzaw) 44, 455-470 (1999)

142. J. Buffle, M.-L. Tercier-Waeber, N. Parthasarathy, M. Koudelka-Hep, F. Graziottin
Techniques for in situ analysis and speciation of trace elements in aquatic
Media
Chemistry Forum 99, Sklad i druk: Firma Wydawnicka K2 (1999)

141. M.-L. Tercier-Waeber, J. Buffle, F. Graziottin, M. Koudelka-Hep Novel voltammetric
probe for in situ trace element monitoring
Sea Technology 40, 74-79 (1999)

140. F. Guyon, N. Parthasarathy, J. Buffle Mechanism and kinetics of Cu(II) transport
through diaza-crown-ether-fatty acid supported liquid membrane
Anal.Chem., 71, 819-826 (1999)

139. S. Stoll, J. Dayantis, J. Buffle Multidimensional statistical properties of simple sampling
chains in the continuum
Macromol. Theory Simul., 8, 119-128 (1999)

138. J. Zhang, C. Huguenard, C. Scarnecchia, R. Menghetti, J. Buffle Stabilization and
destabilization of hematite suspensions by neutral and anionic polyacrylamide
Colloids and Surfaces, 151, 49-63 (1999)

137. W. Davison, J. Buffle, R. De Vitre Voltammetric characterization of a dissolved iron
sulphide species by laboratory and field studies
Anal.Chim.Acta, 377, 193-203 (1998)

136. R. Ferretti, J. Zhang and J. Buffle Flocculation of hematite with polyacrylic acid: fractal
structures in the reaction- and diffusion-limited aggregation regimes
Journal of Colloid and Interface Science, 208, 509-517 (1998)

135. P. H. Santschi, E. Balnois K. J. Wilkinson, J. Zhang, J. Buffle, L. Guo Fibrillar
polysaccharides in marine macromolecular organic matter as imaged by atomic force
microscopy and transmission electron microscopy
Limnol. Oceanogr., 43(5), 896-908 (1998)

134. J. Buffle, K.J. Wilkinson, S. Stoll, M. Filella, J. Zhang A generalized description of
aquatic colloidal interactions: the three-colloidal component
approach
Environ.Sci.&Technol. 32, 2887-2899 (1998)

133. K. Startchev, J. Zhang, J. Buffle Applications of fluorescence correlation spectroscopy -
Particle size effect
J. Colloid and Interface Sc., 203, 189-196 (1998)

132. M.-L. Tercier-Waeber, C. Belmont-Hébert, J. Buffle Real-time continuous Mn(II)
monitoring in lakes using a novel voltammetric in-situ profiling
system
Env.Sci.&Techn., 32, 1515-1521 (1998)

131. C. Belmont-Hébert, M.-L. Tercier, J. Buffle Gel-integrated microelectrode arrays for
direct voltammetric measurements of heavy metals in natural waters and other complex
media
Anal.Chem., 70, 2949-2956 (1998)

130. M.F. Paugam, J. Buffle Comparison of carrier-facilitated copper(II) ion transport
mechanisms in a supported liquid membrane and in a plasticized cellulose triacetate
membrane
J. Membrane Sci 147, 207-215 (1998)

129. F. Wang, A. Tessier, J. Buffle Voltammetric determination of elemental sulfur in pore
Waters
Limnol. Oceanography, 43(6), 1353-1361 (1998)

128. M.-L. Tercier, J. Buffle, F. Graziottin A novel voltammetric in-situ profiling system for
continuous, real-time monitoring of trace elements in natural waters
Electroanalysis, 10, No. 6, 355-363 (1998)

127. S. Stoll, J. Buffle Computer simulation of flocculation processes: the roles of polymer
conformation and polymer/colloid concentration ratio on the aggregate structures
Journal of Colloid and Interface Science, 205, 290-304 (1998)

126. N. Parthasarathy, M. Pelletier, J. Buffle Hollow fiber based supported liquid membrane:
a novel analytical system for trace metal analysis
Anal.Chim.Acta, 350, 183-195 (1997)

125. J.R. Lead, W. Davison, J. Hamilton-Taylor, J. Buffle Characterizing colloidal material
in natural waters: the need for in situ analysis
Aquatic Geochemistry, 3, 213-232 (1997)

124. K.J. Wilkinson, A. Joz-Roland, J. Buffle Different roles of pedogenic fulvic acids and
aquagenic biopolymers on colloidaggregation and stability in freshwaters
Limnology and Oceanography, 42, 1714-1724 (1997)

123. J. Buffle, M.L. Tercier, N. Parthasarathy, K. Wilkinson Analytical Techniques for the in
situ measurement and speciation of trace compounds in natural waters
Chimia 51, 690-693 (1997)

122. J. Buffle, K. J. Wilkinson, M.-L. Tercier and N. Parthasarathy In situ monitoring and
speciation of trace metals in natural waters
Annali di Chimica 87, 67-82 (1997)

121. M. Filella, J. Zhang, M. Newman, J. Buffle Analytical applications of photon
correlation spectroscopy for size distribution measurements of natural colloidal
suspensions: capabilities and limitations
Colloids and Surfaces, 120, 27-46 (1997)

120. R. Ferretti, J. Zhang, J. Buffle Kinetics of hematite aggregation by polyacrylic acid:
effect of polymer molecular weights
Colloids and Surfaces, 121, 203-215 (1997)

119. K.J. Wilkinson, J. Nègre, J. Buffle Coagulation of colloidal material in surface waters.
The role of organic matter
J.Contaminant Hydrology, 26, 229-243 (1997)

118. J. Chorover, J.J. Zhang, M. K. Amistadi and J. Buffle Comparison of hematite
coagulation by charge screening and phosphate adsorption: differences in aggregate
structure.
Clay and Clay Minerals, 45 (5), 690-708 (1997)

117. N. Belzile, J. Pizarro, M. Filella and J. Buffle
Sediment diffusive fluxes of Fe, Mn and P in a eutrophic lake: contribution from lateral
vs bottom sediments
Aquatic Sciences 58, 4, pp.327-354 (1996)

116. M.V. Biber, F. Gulaçar, J. Buffle Principal groups of organic matter in a eutrophic lake
using pyrolysis-GC-MS
Environ.Sci.Technol, 30, 3501-3507 (1996)

115. M.-L. Tercier, J. Buffle Antifouling membrane-covered voltammetric microsensor for in
situ measurements in natural waters
Anal.Chem., vol. 68, 20, pp. 3670-3678 (1996)

114.Y. Chen, J. Buffle Physicochemical and microbial preservation of colloid
characteristics of natural water samples II. Physico-chemical and microbial
evolution
Water Research, Vol. 30, 9, 2185-2192 (1996)

113. Y. Chen, J. Buffle Physicochemical and microbial preservation of colloid
characteristics of natural water samples I: Experimental conditions
Water Research, Vol. 30, 9, 2178-2184 (1996)

112. C. Belmont, M.L. Tercier, J. Buffle, J.C, Fiaccabrino, M. Koudelka-Hep Mercury-plated
iridium-based microelectrode arrays for trace metals detection by voltammetry:
optimumconditions and reliability
Anal.Chim.Acta, 329, 203-214 (1996)

111. W. Krasner, J.P. Croué, J. Buffle, E.M. Perdue Three approaches for the
characterization of NOM
J.Am.Water Works Assoc., 66-79 (1996)

110. S. Stoll and J. Buffle Computer simulation of bridging flocculation processes: the role
of colloid to polymer concentration ratio on aggregation kinetics
J. of Colloid andInterface Sc., 180, 548-563 (1996)

109. J. Zhang, J. Buffle Multi-method determination of the fractal dimension of hematite
Aggregates.Colloids and Surfaces (A) 107, 175-187 (1996)

108. J. Buffle, G.G. Leppard Characterization of aquatic colloids and macromolecules: Part
II, The key role of physical structures on analytical results (Feature Article/Critical
Review)
Environ. Sci. Techn., vol. 29, 9, 2176-2184 (1995)

107. J. Buffle, G.G. LeppardCharacterization of aquatic colloids and macromolecules: Part I,
Structure and behaviour of colloidal material (Feature article/Critical Review)
Environ. Sci. Techn., vol. 29, 9, 2169-2175 (1995)

106. J. Buffle, M. Filella Physico-chemical heterogeneity of natural complexants:
Clarification
Anal. Chim. Acta, 313, 144-150 (1995)

105. S. Stoll, J. Buffle Computer simulation of colloid and macromolecules aggregate
formation
Chimia, 49, 300-307 (1995)

104. J. Zhang, J. Buffle Kinetics of Hematite aggregation by polyacrylic acid: importance of
charge neutralization
J. Colloid. Interface Science, 174, 500-509 (1995)

103. J. Buffle, M. Filella, J. Zhang Biophysical environmental chemistry : a new frontier for
Chemistry
Chimia, 49, 102-109 (1995)

102. J. Pizarro, N. Belzile, M. Filella, G.G. Leppard, J.C. Nègre, D. Perret, J. Buffle
Coagulation sedimentation of submicron iron particles in a eutrophic lake
Water Research, 29, 617-632 (1995)

101. R.M. Town, M.L. Tercier, N. Parthasarathy, F. bujard, S. Rodak, C. Bernard, J. Buffle A
versatile macro-to micro size stationary mercury drop electrode
Anal. Chim. Acta, 302, 1-8 (1995)

100. M.L. Tercier, N. Parthasarathy, J. Buffle Reproducible, reliable and rugged mercury-
plated Ir-based microelectrode for in-situ measurements in natural waters.
Electroanalysis, 7, No 1, pp. 55-63 (1995)

99. K.J. Wilkinson, S. Stoll, J. Buffle Characterization of NOM-colloid aggregates in
surface waters: coupling transmission electron microscopy staining techniques and
mathematical modelling
Fresenius J. Anal. Chem., 351, 54-62 (1995)

98. Y. Chen and J. Buffle Chemical composition determination of suspended mineral
particles and colloidal fractions of river samples
Intern. J.Environ.Anal.Chem., 57, 125-133 (1994)

97. A.M. Mota, ML. Simoes Gonçalves, J.P. Farinha, J. Buffle Adsorption of poly(ethylene
glycol)s on mercury/aqueous solution interface 2. Influence of the chain length
Colloids and Surfaces, A 90, 279-283 (1994)

96. A.M. Mota, ML. Simoes Gonçalves, J.P. Farinha, J. Buffle Adsorption of poly(ethylene
glycol)s on mercury/aqueous solution interface 1. Kinetic of PEG 8000 adsorption
Colloids and Surfaces, A 90, 271-278 (1994)

95. O.C. Keller, S. Poitry, J. Buffle A hollow fibre supported liquid membrane system for
metal speciation and preconcentration: calculation of the response time.
J.Electroanal.Chem. 378, 165-175 (1994)

94. N. Parthasarathy and J. Buffle Capabilities of supported liquid membranes for metal
speciation in natural waters:application to copper speciation.
Anal.Chim.Acta, 284 , 649-659 (1994)

93. .M. Newman, M. Filella, Y. Chen, JC. Nègre, D. Perret, J. Buffle Submicron Particles in
the rhine river. II. Comparison of field observations and model predictions.
Water Research, 28 , 107-118 (1994)

92. D. Perret, M. Newman, JC. Nègre, Y. Chen, J. Buffle Submicron particles in the Rhine
river. I. Physico-chemical characterization.
Water Research, 28 , 91-106 (1994)

91. M. Filella, J. Buffle Factors controlling the stability of submicron colloids in natural
waters. Colloids and Surfaces A: Physico-chemical and Engineering Aspects, 73 ,
255-273 (1993)

90. M. Filella, J. Buffle, G. Leppard Characterization of submicron colloids in freshwaters.
Evidence for their bridging by organic structures.
Water Science and Technology, 27 , 91-102 (1993)

89. ML. Tercier, J. Buffle In situ voltammetric measurements in natural waters. Future
prospects and challenges.
Review article. Electroanalysis 5 187-200 (1993)

88. R. Jermann, ML. Tercier, J. Buffle Pressure insensitive solid-state reference electrode for
in-situ voltammetric measurements in lake water.
Anal.Chim.Acta 269 49-58 (1992)

87. H.P. van Leeuwen, J. Buffle, M. Lovric Reactant adsorption in analytical pulse
voltametry. Methodology and recommendations.
Pure and Appl. Chem. 64 1015-1028 (1992)

86. N. Parthasarathy, J. Buffle Supported liquid membrane for analytical separation of
transition metal ions. Part II: Appraisal of lipophilic 1,10 didecyl diaza 18 crown 6 as
metal ion carrier in the membrane
Anal. Chim. Acta 254 9-19 (1991)

85. N. Parthasarathy, J. Buffle Supported liquid membrane for analytical separation of
transition metal ions. Part I: Complexation properties of 1,10 didedyl diaza 18 crown 6.
Anal. Chim. Acta 254 1.7 (1991)

84. R.R. De Vitre, M.-L. Tercier, M. Tsacopoulos, J. Buffle A mercury plated Iridium based
microelectrode: preparation and some properties.
Anal. Chim. Acta 249 419-425 (1991)

83. D. Perret, G.G. Leppard, M. Muller, N. Belzile, R.R. De Vitre, J. Buffle; Electron
microscopy of aquatic colloids: non perturbing preparation of specimens in the field
Water Research 25 1333-1343 (1991)

82. R.R. De Vitre, M.-L. Tercier, J. Buffle In situ voltammetric measurements in natural
waters, the advantages of microelectrodes.
Analytical Proceedings 28 74-75 (1991)

81. H.P. van Leeuwen, J. Buffle Voltammetry of heterogeneous metal complex systems.
Theoretical analysis of the effects of association/dissociation kinetics and the ensuing
lability criteria.
J. Electroanal. Chem. 296 359-370 (1990)
80. M.-L. Tercier, J. Buffle, A. Zirino, R.R. De Vitre In situ voltammetric measurement of
trace elements in lakes and oceans.
Anal. Chim. Acta 237 429-437 (1990)

79. J. Buffle, R.S. Altmann, M. Filella, A. Tessier Complexation by natural heterogeneous
compounds: Site Occupation Distribution Function, a normalized description of metal
complexation.
Geochim. Cosmochim. Acta 54 1535-1553 (1990)

78. G.G. Leppard, B.K. Burnisson, J. Buffle Transmission electron microscopy of the natural
organic matter of surface waters.
Anal. Chim. Acta 232 107-121 (1990)

77. J. Buffle, R.S. Altmann, M. Filella The effect of physico-chemical heterogeneity of
natural complexants. Part II: The buffering action and role of their background sites.
Anal. Chim. Acta 232 225-237 (1990)

76. M. Filella, J. Buffle, H.P. van Leeuwen The effect of physico-chemical heterogeneity of
natural ligands. Part I: Voltammetry of labile metal-fulvic complexes.
Anal. Chim. Acta 232 209-223 (1990)

75. M.-L. Tercier, J. Buffle Photomicroscopic measurement of the diffusion layer around
mercury drop electrodes. Part II: Choice of the optimum conditions.
Electroanalysis 2 99-105 (1990)

74. M.-L. Tercier, C. Bernard, F. Bujard, S. Rodak, J. Buffle Photomicroscopic measurement
of the diffusion layer around mercury drop electrodes. Part I: description of the
electrochemical system.
Electroanalysis 2 89-97 (1990)

73. G.G. Leppard, J. Buffle, R.R. De Vitre, D. Perret Colloidal iron hydroxy-phosphate. The
sizing and morphology of an amorphous species in relation to partitionning phenomena.
Sci. Tot. Environ. 87/88 345-354 (1989)

72. M. Penczek, Z. Stojek, J. Buffle Theoretical comparison of linear scan and staircase
anodic stripping voltammetry. Restricted and infinite diffusion.
J. Electroanal. Chem. 270 1-6 (1989)

71. .P. van Leeuwen, R.F.M.J. Cleven, J. Buffle Voltammetric techniques for complexation
measurements in natural aquatic media: role of the size of macromolecular ligand and
dissociation kinetics of complexes.
Pure and Applied Chem. 61 255-274 (1989)

70. J. Buffle, R.R. De Vitre, D. Perret, G.G. Leppard Physico-chemical characteristics of a
colloidal iron phosphate species formed at the oxic-anoxic interface of a eutrophic lake
Geochim. Cosmochim. Acta 53 399-408 (1989)

69. J. Zumstein, J. Buffle Circulation of pedogenic and aquogenic organic matter in a
eutrophic lake.
Water Research 23 129-239 (1989)

68. W. Davison, J. Buffle, R.R. De Vitre Interpretation of speciation measurements: a case
study. Direct polarographic measurement of O2, Fe(II), Mn(II), S(-II) and related
species in anoxic waters.
Pure and Applied Chem. 60 1535-1548 (1988)

67.G.G. Leppard, J. Buffle, R.R. De Vitre, D. Perret The ultrastructure and physical
characteristics of a distinctive colloidal iron particulate isolated from a small eutrophic
lake.
Arch. Hydrobiol. 113 405-424 (1988)

66. R.S. Altmann, J. Buffle The use of differential equilibrium functions for interpretation of
metal binding in complex ligand systems: its relation to site occupation and site affinity
distribution.
Geochim. Cosmochim. Acta 52 1505-1519 (1988)

65. R.R. De Vitre, J. Buffle, D. Perret, R. Baudat A study of iron and manganese
transformations at the O2/S(-II) transition layer in a eutrophic lake (Lake Bret,
Switzerland) a multimethod approach.
Geochim. Cosmochim Acta 52 1601-1613 (1988)

64. S.P. Kounaves, J. Buffle An Iridium based mercury film electrode. Part II: Comparison
of mercury-film electrode beaviours: theory versus reality.
J. Electroanal. Chem. 239 113-123 (1988)

63..J. Buffle, J.P. Bernhard, M.L. Tercier Extension of the sensitivity limit of amalgam
electrodes in dilute aquatic media, based on the study of their oxidation process.
J. Electroanal. Chem. 236 67-86 (1987)

62. J.P. Bernhard, J. Buffle, N. Parthasarathy Application of amalgam electrodes in studies of
heavy metal complexation under natural water conditions
Anal. Chim. Acta 200 191-211 (1987)

61. R.R. De Vitre, F. Bujard, C. Bernard, J. Buffle A novel in situ cascade filtration unit
specifically designed for field studies of anoxic waters.
Intern. J. Environ. Anal. Chem. 31 145-163 (1987)

60. J. Buffle, O. Zali, J. Zumstein, R.R. De Vitre Analytical methods for the direct
determination of inorganic and organic species: seasonal changes of iron, sulfur and
pedogenic and aquogenic organic constituents in the eutrophic lake Bret (Switzerland)
Sci. of the Tot. Environ. 64 41-59 (1987)

59. J. Buffle, A.M. Mota, M.L. Gonçalves Adsorption of fulvic-like organic ligands and their
Cd and Pb complexes, at the mercury electrode.
J. Electroanal. Chem. 223 235-262 (1987)

58. J. Buffle, J.J. Vuilleumier, M.L. Tercier, N. Parthasarathy Voltammetric study of humic
and fulvic substances. Part V. Interpretation of metal ion complexation measured by
anodic stripping voltammetric methods.
Science of the Tot. Environ. 60 75-96 (1987)

57. S.P. Kounaves, J. Buffle An Iridium based mercury-film electrode. Part I. Selection of
substrate and preparation.
J. Electroanal. Chem. 216 53-69 (1987)

56. S.P. Kounaves, J. Buffle Deposition and stripping properties of mercury on Iridium
electrodes.
J. Electrochem. Soc. 133 2495-2498 (1986)

55. G.G. Leppard, J. Buffle, R. Baudat A description of the aggregation properties of aquatic
pedogenic fulvic acids. Combining physico-chemical data and microscopical observations.
Water Research 20 185-196 (1986)

54. N. Parthasarathy, J. Buffle, W. Haerdi Study of interaction of polymeric aluminium
hydroxide with fluoride.
Can. J. Chem. 64 24-29 (1986)

53. N. Parthasarathy, J. Buffle, W. Haerdi Combined use of calcium salt and polymeric
aluminium hydroxide for defluoridation of waste waters.
Water Research 20 443-448 (1986)

52. A.M. Almeida Mota, J. Buffle, S.P. Kounaves, M.L. Simoes Gonçalves The importance
of concentration effects at the electrode surface in anodic stripping voltammetric
measurements of complexation of metal ions at natural water concentrations.
Anal. Chim. Acta 172 13-30 (1985)

51. J. Buffle, A.M. Mota, M.L. Gonçalves Determination of stability constants using ASV
technique (Surface concentration effect)
Portugaliae Electrochimica Acta 3 293-310 ((1985)

50. N. Parthasarathy, J. Buffle, W. Haerdi The effect of calcium and sulphate ions on the
removal of fluoride from fluoridated waste water by precipitation with polymeric
aluminium hydroxide.
Revue Française des Sciences de l'Eau 4 181-192 (1985)

49. J. Buffle, N. Parthasarathy, W. Haerdi Importance of speciation methods in analytical
control of water treatment with application to fluoride removal from waste waters.
Water Research 19 7-23 (1985)

48. N. Parthasarathy, J. Buffle Study of polymeric aluminium(III) hydroxide solution for
application in waste water treatment. Properties of the polymer and optimal conditions of
preparations.
Water Research 19 25-36 (1985)

47. C. Staub, J. Buffle, W. Haerdi Measurement of complexation properties of metal ions in
natural conditions by ultrafiltration: influence of various factors on the retention of
metals and ligands by neutral and negatively charged membranes.
Anal. Chem. 56 2843-2849 (1984)

46. J. Buffle, C. Staub Measurement of complexation properties of metal ions in natural
conditions by ultrafiltration: measurement of equilibrium constants for complexation of
Zinc by synthetic and natural ligands.
Anal. Chem. 56 2837-2842 (1984)

45. F. Dalang, J. Buffle, W. Haerdi Study of the influence of fulvic compounds on the
adsorption of Cu(II) ions at the kaolinite surface.
Env. Sci. Techn. 18 135-141 (1984)

44. C. Staub, J. Buffle, W. Haerdi Application of ultrafiltration for the determination of
stability constants of Zn(II) complexes with regards to metal speciation in natural waters.
in Heavy Metals in the Environment. Vol 2 pp. 1227-1230Proceedings of an Int. Conf.
held at Heidelberg (1983)

43. S.S. Bates, A. Tessier, P.G.C. Campbell, J. Buffle Zinc adsorption and assimilation by
chlamydomonas variabilis and scenedesmus subspicatus (Chlorophycae) grown in
semicontinuous culture.
J. of Phycology 18 521-529 (1982)

42. J. Buffle, P. Deladoey Analysis and characterization of natural organic matters in fresh
waters.II: Comparison of the properties of waters of various origins and their annual
trends.
Schweiz. Z. Hydrol. 44 363-391 (1982)

41. J. Buffle, P. Deladoey, J. Zumstein, W. Haerdi Analysis and characterization of natural
organic matters in fresh waters.I: Study of analytical techniques.
Schweiz. Z. Hydrol. 44 325-362 (1982)

40. J. Buffle L'enseignement multidisciplinaire de la chimie de l'environnement à l'Université
de Genève.Chimia 36 99-100 (1982)
Analusis 10 247-249 (1982)

39. J. Buffle, M. Spoerri Role of the diffusion process on the response time of CO2
electrodes.
J. Electroanal. Chem. 129 67-88 (1981)

38. J. Buffle Speciation of trace elements in natural waters.
Trends in Anal. Chem. 1 90-95 (1981)

37. J. Buffle Calculations of the surface concentration of the oxidized metal during the
stripping step in the anodic stripping techniques and its influence on speciation
measurements in natural waters.
J. Electroanal. Chem. 125 273-294 (1981)

36. J. Buffle, A. Cominoli Voltammetric study of humic and fulvic substances. IV: Behaviour
of fulvic substances at the mercury-water interface.
J. Electroanal. Chem. 121 273-299 (1981)

35. G.D. Christian, J. Buffle, W. Haerdi
Study of Selenium(IV) at a dropping mercury electrode by cyclic voltammetry with
triangular polarization.
J. Electroanal. Chem. 109 187-194 (1980)

34. J. Buffle A critical comparison of complexation studies of Cu(II) by fulvic and humic
substances.
Anal. Chim. Acta 118 29-44 (1980)

33. J. Buffle, P. Deladoey, F-L. Greter, W. Haerdi Study of the complexation parameters of
Cu(II) by humic and fulvic substances.
Anal. Chim. Acta 116 255-274 (1980)

32. A. Cominoli, J. Buffle, W. Haerdi Voltammetric study of humic and fulvic substances. III:
Comparison of the capabilities of the various polarographic techniques for the analysis
of humic and fulvic substances.
J. Electroanal. Chem. 110 259-275 (1980)

31. J. Buffle Le rôle des méthodes électrochimiques en analyse des eaux
.CEBEDEAU 426 165-176 (1979)

30. J. Buffle, F-L. Greter Voltammetric study of humic and fulvic substances. II: Mechanism
of reaction of the Pb- fulvic complexes on the mercury electrode.
J. Electroanal. Chem. 101 231-251 (1979)

29. F-L. Greter, J. Buffle, W. Haerdi Voltammetric study of humic and fulvic substances. I:
Behaviour of humic and fulvic complexes of lead on the mercury electrode.
J. Electroanal. Chem. 101 211-229 (1979)

28. J. Buffle, P. Deladoey, W. Haerdi The use of ultrafiltration for the separation and
fractionation of organic ligands in fresh waters.
Anal. Chim. Acta 101 339-357 (1978)

27. W. Haerdi, Cl. Bergerioux, J.P. Blanc, S. Dogan, J. Buffle Analyse des éléments traces
dans les eaux naturelles par activation neutronique et absorption atomique.
Techniques et Sciences Municipales 113-116 (Mars 1978)

26. J. Buffle, A. Cominoli, F-L. Greter, W. Haerdi Voltammetric behaviour of humic and
fulvic substances of natural waters.
Proc. Analyt. Div. Chem. Soc. 59-61 (1978)

25. N. Parthasarathy, J. Buffle, W. Haerdi A study of the behaviour of solid-state membrane
electrodes. IV: Experimental studies of the response time.
Anal. Chim. Acta 93 121-128 (1977)

24. J. Buffle, N. Parthasarathy A study of the behaviour of solid-state membrane electrodes.
III: A model for the response time
Anal. Chim. Acta 93 111-120 (1977)

23. J. Buffle, A.E. Martell Metal-ion catalysed oxydation of o-dihydroxy-aromatic
compounds by oxygen. II: Complexes of 1-2 dihydroxy-naphtalene-4-sulfonate with
Fe(III) and Fe(II).
Inorganic Chemistry 16 2225-2229 (1977)

22. J. Buffle, A.E. Martell Metal-ion catalyzed oxydation of o-dihydroxy aromatic
compounds by oxygen. I: Study of the red-ox and acid-base properties of the system 1-2
naphtoquinon-4-sulfonate/1-2 dihydroxy-naphtalene-4-sulfonate.
Inorganic Chemistry 16 2221-2225 (1977)

21. J. Buffle, F-L. Greter, W. Haerdi Measurement of complexation properties of humic and
fulvic acids in natural waters with lead and copper ion-selective electrodes.
Anal. Chem. 49 216-222 (1977)

20. J. Buffle, G. Nembrini Study of the mecanism of the electrochemical reduction of
hydrolysed iron(III) species, in connection with their colloidal properties.
J. Electroanal. Chem. 76 101-119 (1977)

19. J. Buffle Les substances humiques et leurs interactions avec les ions minéraux.
Techniques et Sciences Municipales 3-10 (janvier 1977)

18. J. Buffle, F-L. Greter, G. Nembrini, J. Paul, W. Haerdi Capabilities of voltammetric
techniques for water quality control problems.
Z. Anal. Chem. 282 339-350 (1976)

17. G. Nembrini, J. Buffle, W. Haerdi Voltammetric behaviour of iron(III) hydrolysed
solutions and characterization of the reducible species.
J. Coll. Int. Science 57 327-336 (1976)

16. J.C. Landry, J. Buffle, W. Haerdi, M. Leventhal, G. Nembrini Contribution à l'étude des
hydroxocomplexes de Fe(III) en solution aqueuse.
Chimia 29 253-256 (1975)

15. J. Buffle, N. Parthasarathy, W. Haerdi Study of the behaviour of the solid-state membrane
electrodes. Part II: Role of the adsorption on fluoride ion selective electrode and
determination of solubility of the membrane.
Anal. Chim. Acta 68 253-266 (1974)

14. J. Buffle, J.C. Landry, W. Haerdi Avantages et limitations des électrodes sélectives dans
l'analyse des eaux.
Techniques et Sciences Municipales 69 547-554 (1974)

13. N. Parthasarathy, J. Buffle, D. Monnier Study of the behaviour of the solid-state
membrane electrodes. Part I: Role of the various factors on the limit of sensitivity of Cl-
and F- electrodes. Anal. Chim. Acta 68 185-196 (1974)
12. N. Parthasarathy, J. Buffle, J.C. Landry, C. Birraux, J.F. Monn, M.C. Terraz, W. Haerdi
Quelques considérations sur l'utilisation des électrodes sélectives et leur limite de
sensibilité.
Chimia 27 368-371 (1973)

11. J. Buffle, M. Pelletier, D. Monnier Chronopotentiometric study of oxydation of some
diluted amalgams in the presence of traces of oxygen dissolved in aqueous solution. Part
II: study of the influence of various parameters on the reaction rate.
J. Electroanal. Chem. 43 185-195 (1973)

10. J. Hubmann, J. Buffle, D. Monnier Determination of trace amounts of silver(I) by
polarographic, anodic stripping and chronopotentiometric methods at mercury electrode.
Studies in aqueous and non aqueous media.
Anal. Chim. Acta 62 393-404 (1972)

9. N. Parthasarathy, J. Buffle, D. Monnier Errors in the addition method. III: Experimental
verification of errors by means of fluoride selective electrode.
Anal.Chim. Acta 59 447-452 (1972)

8. J. Buffle Errors in the addition method. II: Theoretical calculation of systematic errors.
Anal. Chim. Acta 59 439-445 (1972)

7. J. Buffle, N. Parthasarathy, D. Monnier Errors in the addition method. I: Theoretical
calculation of statistical errors.
Anal. Chim. Acta 59 427-438 (1972)

6. J. Buffle, N. Parthasarathy, D. Monnier Influence de la constitution du milieu et des
conditions opératoires sur la réponse des électrodes sélectives
Chimie 25 223-227 (1971)

5. M. Pelletier, J. Buffle, D. Monnier Etude chronopotentiométrique de l'oxydation de
quelques amalgames dilués en présence de traces d'oxygène
Chimie 25 61-62 (1971)

4. J. Buffle Contribution à l'étude du dosage de submicrotraces de fer par polarographie
inverse.
Thèse de doctorat ès sciences chimiques n° 1485, Université de Genève, (1969)

3. W. Haerdi, J. Buffle, D. Monnier Contribution à l'étude du dosage de submicrontraces de
fer par polarographie inverse sur goutte de mercure pendante. II: Etude des réactions
secondaires.
J. Electroanal. Chem. 23 89-98 (1969)

2. W. Haerdi, J. Buffle, D. Monnier Contribution à l'étude du dosage de submicrontraces
de fer par polarographie inverse sur goutte de mercure pendante. I: Etat du fer sur
l'électrode et mécanisme d'oxydation électrochimique.
J. Electroanal. Chem. 23 81-89 (1969)

1. J. Buffle, D. Monnier, W. Haerdi Etude analytique du dosage de submicrotraces de fer
par polarographie inverse.
Chimie 21 578-581 (1967)