Photophysics and Photochemistry of Transition Metal Compounds | |
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Chromium(III)-trisoxalate,[Cr(ox)3]3- (ox = C2O42-), incorporated into polymeric networks of composition [NaCr(ox)3][MII(bpy)3] and [NaCr(ox)3][MIII(bpy)3]ClO4 (bpy= 2,2'-bipyridine, MII = Zn, Fe, Ru; MIII = Rh, Cr), results in interesting features ranging from phonon-assisted and resonant energy migration within the R1 line the 2E state to persistent spectral side-hole burning via the latter, and manifestations of specific nearest-neighbour π–π interactions between bipyridine and oxalate. |
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Last update Friday December 08 2017