Stay informed of our last publications with our atom feed Atom feed

 1999 

1999

  • Cooperative phenomena and light-induced bistability in iron(II) spin-crossover compounds
    , J. Jeftic, H. Romstedt, R. Hinek and H. Spiering
    Coordination Chemistry Reviews, 190-192 (1999), p471-491
    Keywords: iron(II) coordination compounds; spin-crossover; cooperative effects; high-spin<->low-spin relaxation; bistability
    DOI:10.1016/S0010-8545(99)00111-3 | unige:2740 | Abstract | Article HTML | Article PDF
 
In iron(II) spin-crossover compounds, the transition from the 1A1 low-spin state at low temperatures to the 5T2 high-spin state at elevated temperatures is accompanied by a large increase in metal-ligand bond lengths. The resulting elastic interactions may be pictured as an internal pressure which is proportional to the concentration of the low-spin species. Because pressure stabilises the low-spin state relative to the high-spin state this results in a positive feedback. Thermal transition curves in neat iron(II) spin-crossover compounds are thus invariable much steeper than in diluted mixed crystals, and the high-spin→low-spin relaxation following the light-induced population of the high-spin state at low temperatures is self-accelerating. Strong interactions give rise to a thermal hysteresis, and light-induced bistabilities may be observed for compounds with initially a high-spin ground state and the potential for a light-induced population of the low-spin state. For such compounds, the increasing internal pressure may stabilise the low-spin state sufficiently so that it becomes the molecular ground state above some critical light-induced low-spin fraction. Secondary effects of the elastic interactions include crystallographic phase transitions, inhomogeneous distributions of sites, and anomalies such as steps in the transition curve.

 1999 

Author list

Download this list in format   RIS     EndNote     BibTex     PDF    XML  



Last update Friday May 17 2013