Dr Hans Hagemann homepage


Dept. of Physical Chemistry
University of Geneva
30 Quai Ernest Ansermet
CH - 1211 GENEVE 4


Tel : +41 22 37 96539
Fax : +41 22 37 96103

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Email: Hans-Rudolf.Hagemann@unige.ch

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Recent research results :

Ref1: Effect of Temperature and Pressure on Emission Lifetime of Sm2+ Ion Doped in MFX (M=Sr, Ba; X=Br, I) Crystals Ref2: Study of Surfactant Alcohols with various Chemical Motives at the Hydrophilic/Hydrophobic Interface Ref3: Vibrational spectra and structure of borohydrides Ref4: Improved photoluminescence and afterglow of CaTiO3:Pr3+ by ammonia treatment Ref5: Effect of Pressure on the Free Ion and Crystal Field Parameters of Sm2+ in BaFBr and SrFBr Hosts Ref6: Bimetallic Borohydrides in the System M(BH4)2–KBH4 (M = Mg, Mn): On the Structural Diversity Ref7: A mixed-cation mixed-anion borohydride NaY(BH4)2Cl2 Ref8: The influence of defects formed by Ca excess and thermal post-treatments on the persistent luminescence of CaTiO3:Pr    Cycle through references
Effect of Temperature and Pressure on Emission Lifetime of Sm2+ Ion Doped in MFX (M=Sr, Ba; X=Br, I) Crystals
Prodipta Pal, Tiphaine Penhouët, Vincenza D'Anna and Hans Hagemann
ref1343

The emission lifetime of Sm2+ ions doped in MFX (M=Ba, Sr; X=Br, I) crystals was investigated as a function of pressure and temperature. The decay of the 5DJ(J=0,1,2) levels showed single exponential relaxation. The analysis of these experiments yielded the position of the lowest 4f55d1 state as well as non-radiative rate constants. These values were compared with those for Sm2+ doped in other matlockite host crystals. The single exponential decrease of the 5D0,1 lifetime as a function of pressure was described considering the increased radiative decay rates of these 5D0,1 levels through electronic mixing between the 4f55d1 and 5DJstates.

Journal of Luminescence, 142 , 2013 , p66 -74



Last modified 2010/01/15 D.L.