TY - JOUR AU - Angulo, Gonzalo AU - Brucka, Marta AU - Gerecke, Mario AU - Grampp, Günter AU - Jeannerat, Damien AU - Milkiewicz, Jadwiga AU - Mitrev, Yavor AU - Radzewicz, Czeslaw AU - Rosspeintner, Arnulf AU - Vauthey, Eric AU - Wnuk, Pawel TI - Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical Reactivity PY - 2016 JF - Physical Chemistry Chemical Physics JA - Phys. Chem. Chem. Phys. SN - 1463-9076 VL - 18 IS - 27 SP - 18460 EP - 18469 L1 - http://arxiv.org/pdf/1603.01521v1 L2 - http://pubs.rsc.org/en/content/articlehtml/2016/cp/c6cp02997c L3 - http://arxiv.org/abs/1603.01521v1 L4 - http://www.unige.ch/sciences/chifi/publis/pics/double/ref01505.png M3 - 10.1039/C6CP02997C UR - http://dx.doi.org/10.1039/C6CP02997C UR - http://arxiv.org/abs/1603.01521v1 N2 - The properties of binary mixtures of dimethylsulfoxide and glycerol, measured by several techniques, are reported. Special attention is given to those properties contributing or affecting chemical reactions. In this respect the investigated mixture behaves as a relatively simple solvent and it is especially well suited for studies on the influence of viscosity in chemical reactivity. This is due to the relative invariance of the dielectric properties of the mixture. However, special caution must be taken with specific solvation, as the hydrogen-bonding properties of the solvent changes with the molar fraction of glycerol. ID - 1505 ER -