• Photoswitching of the Dielectric Constant of the Spin-Crossover Complex [Fe(L)(CN)2]H2O
    S. Bonhommeau, T. Guillon, , P. Demont, J. Sanchez Costa, J.-F. Létard, G. Molnár and A. Bousseksou
    Angewandte Chemie International Edition, 45 (10) (2006), p1625-1629
    DOI:10.1002/anie.200503252 | unige:3635 | Abstract | Article HTML | Article PDF
  
Photoswitching of the dielectric constant has been observed for the first time in the spin-crossover complex [Fe(L)(CN)2]·H2O (L=2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene, see picture). The electrical detection of a photoinduced change in spin state could allow the use of such complexes in optical information-storage devices.



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