• Chromium(III)-trisoxalate, a versatile building block for luminescent materials
    Mia Milos and
    Journal of Luminescence, 133 , 2013, p15-20
    Keywords: chromium(III)-tris-oxalate; energy migration; fluorescence line narrowing; spectral diffusion; persistent spectral hole burning
    DOI:10.1016/j.jlumin.2011.12.053 | unige:24060 | Article HTML | Article PDF
  
Chromium(III)-trisoxalate,[Cr(ox)3]3- (ox = C2O42-), incorporated into polymeric networks of composition [NaCr(ox)3][MII(bpy)3] and [NaCr(ox)3][MIII(bpy)3]ClO4 (bpy= 2,2'-bipyridine, MII = Zn, Fe, Ru; MIII = Rh, Cr), results in interesting features ranging from phonon-assisted and resonant energy migration within the R1 line the 2E state to persistent spectral side-hole burning via the latter, and manifestations of specific nearest-neighbour π–π interactions between bipyridine and oxalate.

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Hauser, Andreas Milos, Mia 
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