• Pd2Au36(SR)24 cluster: structure studies
    Bei Zhang, Sameh Kaziz, Houhua Li, Dawid Wodka, Sami Malola, Olga V. Safonova, Maarten Nachtegaal, Clement Mazet, Igor Dolamic, Jordi Llorca, Elina Kalenius, Latevi Max Lawson Daku, Hannu Häkkinen, Thomas Buergi and Noelia Barrabes
    Nanoscale, 7 (40) , 2015, p17012-17019
    DOI:10.1039/C5NR04324G | unige:75923 | Abstract | Article HTML | Article PDF | Supporting Info
The location of the Pd atoms in Pd2Au36(SC2H4Ph)24, is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd-S bonds, which is supported by far infrared spectroscopy. By comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.

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Kaziz, Sameh Lawson Daku, Latevi Max Li, Houhua Llorca, Jordi Malola, Sami 
Mazet, Clement Nachtegaal, Maarten Safonova, Olga V. Wodka, Dawid Zhang, Bei 
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