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Publication 223  


  1. R. Millet, A. Alexakis,
    “Copper-catalyzed kinetic resolution of 1,3-cyclohexadiene monoepoxide with Grignard reagents”
    Synlett 2007, 435-438.

Chiral ferrocenyl-based diphosphines lead to kinetic ­resolution of 1,3-cyclohexadiene monoepoxide with moderate to good enantioselectivity (up to 90% ee) and good regioselectivity with various Grignard reagents through an anti-SN2′ pathway.

DOI : 10.1055/s-2007-967945 

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