Research Interests

General reviews:

Nitrogen- and sulfur-based Stevens and related rearrangements. In Comprehensive Organic Synthesis, 2nd ed.; Marek, I., Ed. 2012; in press • C. R. Chimie 2010, 13, 985 • Chem. Commun. 2009, 7073 • Chem. Rec. 2007, 7, 275 • Science 2007, 317, 462 • Chimia 2006, 60, 266 • Org. Biomol. Chem. 2005, 3, 15 • Top. Curr. Chem. 2005, 250, 1-41 [reprint] • Chem. Soc. Rev. 2003, 32, 373.

Organometallic reactivity and asymmetric transformations;
Enantioselective C–C, C–N and C–O bond forming reactions

See: Angew. Chem. Int. Ed. 2012, 51, 5847 • Chem. Eur. J. 2012, 18, 6626 • J. Org. Chem. 2012, 77, 6128 • Org. Biomol. Chem. 2012, 10, 966 • Angew. Chem. Int. Ed. 2011, 50, 7308 • Angew. Chem. Int. Ed. 2011, 50, 3677 • Org. Lett. 2011, 13, 1394 • Adv. Synth. Catal. 2010, 352, 3339 • Angew. Chem. Int. Ed. 2010, 49, 7253 • Tetrahedron: Asymmetry 2010, 21, 1611 • Chem. Commun. 2010, 46, 2206 • Org. Biomol. Chem. 2009, 7, 4057 • Adv. Synth. Catal. 2009, 351, 596 • Eur. J. Org. Chem. 2008, 5778 • Chem. Eur. J. 2008, 14, 5737 • Synlett 2008, 1381 • Adv. Synth. Catal. 2008, 350, 1113 • Chem. Commun. 2008, 829 • Pure Appl. Chem. 2008, 80, 967 • J. Am. Chem. Soc. 2008, 130, 1845 • Angew. Chem. Int. Ed. 2007, 46, 8979 • Chimia 2007, 61, 236 • Angew. Chem. Int. Ed. 2007, 46, 2082 • Org. Biomol. Chem. 2007, 5, 501 • Tetrahedron: Asymmetry 2006, 17, 2334 • Tetrahedron Lett. 2006, 47, 5297 • Chimia 2006, 60, 266 • J. Org. Chem. 2005, 70, 5903 • Synlett 2004, 1565 • Tetrahedron Lett. 2002, 43, 8257.

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Synthetic, physical and biological applications of highly stable (chiral) carbenium ions

See: Dalton Trans. 2012, 41, 6777 • Chirality 2012, in press • Photochem. Photobiol. Sci. 2012, 623 • J. Org. Chem. 2011, 76, 2716 • Chem. Sci. 2011, 2, 425 • J. Phys. Org. Chem. 2010, 23, 1049 • Org. Lett. 2010, 12, 1748 • J. Am. Chem. Soc. 2009, 131, 442 • J. Am. Chem. Soc. 2008, 130, 6507 • J. Mass. Spectrom. 2008, 43, 623 • Chirality 2007, 19, 601 • Org. Lett. 2006, 8, 4343 • Chem. Commun. 2006, 2786 • Org. Biomol. Chem. 2006, 4, 224 • Angew. Chem. Int. Ed. 2005, 44, 1879 • Tetrahedron Lett. 2005, 46, 4605 • J. Org. Chem. 2003, 68, 6304 • Angew. Chem. Int. Ed. 2003, 42, 3162.

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NMR enantiodifferentiation of chiral substances

Hexacoordinated phosphorus chemistry

See: Dalton Trans. 2012, 41, 8235 • New. J. Chem. 2011, 35, 2279 • Chem. Eur. J. 2010, 16, 5706 • Dalton Trans. 2009, 8493 • New. J. Chem. 2009, 33, 376 • Chem. Commun. 2008, 829 • Chirality 2008, 20, 313 • Angew. Chem. Int. Ed. 2007, 46, 8979 • Inorg. Chem. 2007, 46, 10717 • Eur. J. Org. Chem. 2007, 3687 • Organometallics 2007, 26, 2141 • Inorg. Chim. Acta 2007, 360, 955 • J. Org. Chem. 2006, 71, 7412 • Chem. Commun. 2006, 850 • Dalton Trans. 2006, 2058 • Angew. Chem. Int. Ed. 2005, 44, 5060 • Chirality 2005, 17, S143 • J. Org. Chem. 2004, 69, 8521 (large scale TRISPHAT resolution) • Inorg. Chem. 2004, 43, 3329 • Chem. Commun. 2003, 2014 • Helv. Chim. Acta 2003, 86, 65 • Org. Lett. 2002, 4, 3939 • Angew. Chem. Int. Ed. 2002, 41, 2317 • Org. Lett. 2000, 2, 4185 • Angew. Chem. Int. Ed. 2000, 39, 3695 • Angew. Chem., Int. Ed. Engl. 1997, 36, 608 and references therein.

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