127. “Stereoselective dimerization of racemic C₃-symmetric Ti(IV) amine triphenolate complexes”
     G. Bernardinelli, T.M. Seidel, E.P. Kündig, L.J. Prins, A. Kolarvoic, M. Mba, M. Pontini, G. Licini,
     Dalton Trans. 2007, 1573-1576.

A novel, mononuclear Ti(IV) amine triphenolate complex obtained by reaction of Ti(OiPr)₄ withtris(2-hydroxy-3-phenylbenzyl)amine bearing phenyl ortho-substituents affords quantitatively and spontaneously the corresponding heterochiral µ-oxo dinuclear compound whereas an analogous chiral, enantiopure complex maintains its mononuclear structure even in the presence of an excess of water.

DOI : 10.1039/b702958f 

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