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Publication 135
- “Synthesis of a Bicyclo[8.3.1]enediyne via Chromium-Mediated Dearomatization of 2,6-Bis(trimethylsilyl)anisole”
S. Lavy, A. Pérez-Luna, E.P. Kündig,
Synlett 2008, 2621-2624.
A novel bicyclo[8.3.1]enediyne was readily synthesized by chromium-mediated dearomatization of 2,6-bis(trimethylsilyl)anisole. The enediyne undergoes Bergman cyclization with a half-life of 14.4 hours at 142 ˚C.
DOI : 10.1055/s-0028-1083513
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