- Chiroptical Detection of a Model Ruthenium Dye in Water by Circularly Polarized-Electrochemiluminescence
Voci, S.; Zinna, F.; Arrico, L.; Grass, S.; Bouffier, L.; Lacour, J.; Di Bari, L.; Sojic, N.
Chem. Commun. 2020, 56, 5989-5992
We demonstrate the possibility to detect selectively the two singleenantiomers of a model [Ru(bpy)3]2+-based dye by circularlypolarized-electrochemiluminescence (CP-ECL). This new aspect ofthe ECL emission combines the chiral information intrinsic to CPLmethods with an electrogeneration of the excited state. Thus, itopens the possibility to perform ECL-based bioassays or microscopywith efficient chiral dyes.
DOI : 10.1039/d0cc01571g
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