Publication 29 of year 2021

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  1. Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
    Viñas-Lóbez, J.; Levitre, G.; de Aguirre, A.; Besnard, C.; Poblador-Bahamonde, A. I.; Lacour, J.
    ACS Org. Inorg. Au 2021, 1, 11-17

 

Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CH3CN)3][BArF] catalysis. The dual reactivity of these 2-vinyloxymalonates can be used to expand the classical range of cyclizations derived from carbonyl ylide intermediates.

DOI: 10.1021/acsorginorgau.1c00006 

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