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  1. Bhosale, R.; Míšek, J.; Sakai, N.; Matile, S. “Supramolecular n/p-Heterojunction Photosystems with Oriented Multicolored Antiparallel Redox Gradients (OMARG-SHJs)” Chem. Soc. Rev. 2010, 39, 138-149

Directional electron and hole transport is essential in photosynthesis.  Applied to molecular optoelectronics such as organic solar cells, these lessons from nature call for oriented supramolecular n/p-heterojunctions (SHJs) that contain various chromophores and antiparallel redox gradients (OMARGs).  In this tutorial review, we summarize recent progress made toward the construction of OMARG-SHJs.  This conceptually innovative twist added to a timely topic should appeal to the synthetic organic, supramolecular, biological, physical, analytical and materials chemist as well as to the expert in energy and environmental sciences.

DOI: 10.1039/b906115k 

open archive unige:4866 • pdf