322. M. Magrez-Chiquet, M.S.T. Morin, J. Wencel-Delord, S. Drissi Amraoui, O. Baslé, A. Alexakis, C. Crévisy, M. Mauduit,
     “Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition”
     Chem. Eur. J. 2013, 19, 13663-13667.

C—C coupling: DiPPAM 1 and BINAP 2 ligands led to divergent behaviors in the asymmetric conjugate addition (ACA) of dialkylzinc reagents to linear aryldienones, which were applied to the development of a highly selective sequential asymmetric 1,6/1,4-ACA process (see scheme).

DOI : 10.1002/chem.201302649 

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