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Publication 60  

  1. Total Synthesis of β-Bulnesene and 1-Epi-β-bulnesene by Intramolecular Photoaddition
    Oppolzer, W.; Wylie, R. D.
    Helv. Chim. Acta 1980, 63, 1198-1203

dl-β-Bulnesene (1) and dl-1-epi-α-bulnesene (15) have been synthesized starting from the bromide 4 (Schemes 2 and 3). In the key step 9→10 the bonds of the final product were formed by an intramolecular photoaddition. The synthesis was completed by the fragmentation 12→14 and the Wittig reaction 14→15+1.

DOI : 10.1002/hlca.19800630511