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Publication 93  

  1. Michael Addition of Lithio-α-(methyldiphenylsilyl)acetate to Cyclopentenone: A direct synthesis of (±)-methyl jasmonate
    Oppolzer, W.; Guo, M.; Baettig, K.
    Helv. Chim. Acta 1983, 66, 2140-2144

Aprotic 1,4-addition of a lithiated α-(methyldiphenylsilyl)acetate to cyclopentenone and in situ enolate alkylation provides a direct synthesis of (±)-methyl jasmonate (Scheme 3).

DOI : 10.1002/hlca.19830660725