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Publication 105
- Asymmetric diels-alder reactions : facile preparation and structure of sulfonamido-isobornyl acrylates
Oppolzer, W.; Chapuis, C.; Bernardinelli, G.
Tetrahedron Lett. 1984, 25, 5885-5888
The crystalline chiral auxiliaries , and were prepared from camphor-10-sulfonyl chlorides in 2 steps. Their readily accessible acrylates underwent efficient asymmetric diels-alder additions to cyclopentadiene, the topicity of which agrees with X-ray evidence.