225. “On the Decomposition of 1,2,4-Trioxan-5-ones”
     Jefford, C.W.; Vicente, M.G.H.
     Heterocycles 1993, 35, 725-729.

The thermal and chemical properties of six 3,6-substituted 1,2,4-trioxan-5-ones were studied by flash-vacuum thermolysis (FVT) and by treatment with electron-transfer agents. The 1,2,4-trioxan-5-ones exhibited unusual stability both chemically and thermally, but eventually underwent decomposition with loss of carbon dioxide yielding the carbonyl components.

DOI : 10.3987/COM-93-S(T)141 

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