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Publication 104
- Enantioselective and Regioselective Ruthenium-Catalyzed Decarboxylative Etherification of Allyl Aryl Carbonates
Martina Austeri, David Linder, Jérôme Lacour
Chem. Eur. J. 2008, 14, 5737-5741
Simple ligand, catalyst and conditions: The combination of readily-prepared pyridylmonooxazolines (pymox) ligands and [CpRu(CH3CN)3][PF6] affords a regio- and enantioselective decarboxylative etherification of allyl aryl carbonates (see scheme). This is the first successful example of this type of etherification reaction.
Link: http://dx.doi.org/10.1002/chem.200800619
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