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Publication 104  

  1. Enantioselective and Regioselective Ruthenium-Catalyzed Decarboxylative Etherification of Allyl Aryl Carbonates
    Martina Austeri, David Linder, Jérôme Lacour
    Chem. Eur. J. 2008, 14, 5737-5741

Simple ligand, catalyst and conditions: The combination of readily-prepared pyridylmonooxazolines (pymox) ligands and [CpRu(CH3CN)3][PF6] affords a regio- and enantioselective decarboxylative etherification of allyl aryl carbonates (see scheme). This is the first successful example of this type of etherification reaction.


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