13. Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate(V) Ion
    Jérôme Lacour, Catherine Ginglinger, Chantal Grivet, Gérald Bernardinelli
    Angew. Chem., Int. Ed. Eng. 1997, 36, 608-610

Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate(v) ion (1). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X-ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.

DOI: 10.1002/anie.199706081 

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