154. Cationic triangulenes and helicenes: synthesis, chemical stability, optical properties and extended applications of these unusual dyes
     Johann Bosson, Jérôme Gouin, Jérôme Lacour
     Chem. Soc. Rev. 2014, 43, 2824-2840

Cationic triangulenes and helicenes are highly stable carbocations with planar and helical conformations respectively. These moieties are effective dyes with original absorption and emission properties. Over the last decade, they have received greater attention and are considered as valuable tools for the development of innovative applications. In this review, the synthesis of these unique compounds is presented together with their core chemical and physical properties. Representative applications spanning from surface sciences to biology and chemistry are presented.Cationic triangulenes and helicenes are highly stable carbocations with planar and helical conformations respectively. These moieties are effective dyes with original absorption and emission properties. Over the last decade, they have received greater attention and are considered as valuable tools for the development of innovative applications. In this review, the synthesis of these unique compounds is presented together with their core chemical and physical properties. Representative applications spanning from surface sciences to biology and chemistry are presented.

DOI : 10.1039/C3CS60461F 

archive ouverte unige:35007