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Publication 165  

  1. ChemInform Abstract: A Mild and Efficient CH2-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Troeger Bases
    Sandip A. Pujari, Celine Besnard, Thomas Bürgi, Jérôme Lacour
    ChemInform 2015, 46

Oxidation of ethano-Troeger bases (I) and (III) with DDQ in wet nitromethane results in a highly enantiospecific methylene extrusion to afford ring contracted products (II) and (IV) which are significantly more configurationally stable than regular Troeger bases.

DOI: 10.1002/chin.201543111 

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