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  1. Chiroptical Detection of a Model Ruthenium Dye in Water by Circularly Polarized-Electrochemiluminescence
    Silvia Voci, Francesco Zinna, Lorenzo Arrico, Stéphane Grass, Laurent Bouffier, Jérôme Lacour, Lorenzo Di Bari, Neso Sojic
    Chem. Commun. 2020, 56, 5989-5992

We demonstrate the possibility to detect selectively the two singleenantiomers of a model [Ru(bpy)3]2+-based dye by circularlypolarized-electrochemiluminescence (CP-ECL). This new aspect ofthe ECL emission combines the chiral information intrinsic to CPLmethods with an electrogeneration of the excited state. Thus, itopens the possibility to perform ECL-based bioassays or microscopywith efficient chiral dyes.

DOI : 10.1039/d0cc01571g 

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