- Chiroptical Detection of a Model Ruthenium Dye in Water by Circularly Polarized-Electrochemiluminescence
Silvia Voci, Francesco Zinna, Lorenzo Arrico, Stéphane Grass, Laurent Bouffier, Jérôme Lacour, Lorenzo Di Bari, Neso Sojic
Chem. Commun. 2020, 56, 5989-5992
We demonstrate the possibility to detect selectively the two singleenantiomers of a model [Ru(bpy)3]2+-based dye by circularlypolarized-electrochemiluminescence (CP-ECL). This new aspect ofthe ECL emission combines the chiral information intrinsic to CPLmethods with an electrogeneration of the excited state. Thus, itopens the possibility to perform ECL-based bioassays or microscopywith efficient chiral dyes.
open archive unige:137072