8. “Die Chlorierung des Hexamethyl-Dewar-Benzols”
   Burger, U.; Delay, A.
   Helv. Chim. Acta 1973, 56, 1345-1347.

It has been shown that addition of chlorine to hexamethyl-Dewar-benzene is a stereospecific process and yields exclusively 5-endo-chloro-hexamethyl-bicyclo[2.1.1]hexenyl chloride. This supports the suitability of SbCl₅ as a model reagent for olefin chlorination.

DOI : 10.1002/hlca.19730560417 

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