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Publication 131  

  1. Radical cation salts of BEDT-TTF, enantiopure tetramethyl-BEDT-TTF, and TTF-Oxazoline (TTF-Ox) donors with the homoleptic TRISPHAT anion
    François Riobé, Flavia Piron, Céline Réthoré, Augustin M. Madalan, Carlos J. Gómez-García, Jérôme Lacour, John D. Wallis, Narcis Avarvari
    New J. Chem. 2011, 35, 2279-2286

The synthesis and crystal structures of five radical cation salts based on the organic donors bis(ethylenedithio)tetrathiafulvalene, racemic ethylenedithio-methyl-oxazoline-tetrathiafulvalene and the enantiopure tetramethyl-bis(ethylenedithio)tetrathiafulvalene and the D3-symmetric anion tris(tetrachlorobenzenediolato)phosphate(V) TRISPHAT are reported. The donors are fully oxidized and self-assemble in dyads inserted in the channels generated by the packing of the TRISPHAT anions.

DOI: 10.1039/C1NJ20310J 

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