- Ni-Catalyzed Regioselective Hydroalkoxylation of Branched 1,3-Dienes
Tran, G.; Mazet, C.
Org. Lett. 2019, 21, 9124-9127
A highly regioselective Ni-catalyzed hydroalkoxylation of 1,3-dienes is reported. The use of a (P,N) ligand is essential in achieving high levels of selectivity. The optimized protocol operates under particularly mild conditions, it provides access to a broad range of structurally diverse allylic ethers, and tolerates a number of sensitive functional groups.
DOI : 10.1021/acs.orglett.9b03511
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