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Publication 64  

  1. Ni-Catalyzed Regioselective Hydroalkoxylation of Branched 1,3-Dienes
    Gaël Tran, Clément Mazet*
    Org. Lett. 2019, 21, 9124-9127

A highly regioselective Ni-catalyzed hydroalkoxylation of 1,3-dienes is reported. The use of a (P,N) ligand is essential in achieving high levels of selectivity. The optimized protocol operates under particularly mild conditions, it provides access to a broad range of structurally diverse allylic ethers, and tolerates a number of sensitive functional groups.

open archive unige:126350

Editor’s version DOI: 10.1021/acs.orglett.9b03511 

AAM DOI: 10.26037/yareta:fooxao64bfe6zmkqby2terhrm4 

Dataset DOI: 10.26037/yareta:fwinfsjzf5bclneonelvr5tr5a