- Hybrids of Cationic [4]Helicene and N-Heterocyclic Carbene as Ligands for Complexes Exhibiting (Chir)Optical Properties in the Far Red Spectral Window
Tarrieu, R.; Hernandez Delgado, I.; Zinna, F.; Dorcet, V.; Colombel-Rouen, S.; Crévisy, C.; Baslé, O.; Bosson, J.; Lacour, J.
Chem. Commun. 2021, 57, 3793-3796
Synthesis, electronic and structural properties of a chiral NHC bearing a N-bonded cationic [4]helicene moiety are reported. This ligand is used to construct AuI, AuIII and RhI complexes exhibiting far-red (chir)optical properties regardless of the metal.
DOI : 10.1039/D1CC00898F
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