93. Pd-Catalyzed Regiodivergent Arylation of Cyclic Allylboronates
Cheng Zhang, Baptiste Leforestier, Céline Besnard, Clément Mazet*
Chem. Sci. 2025, 16, 22656-22665
92. Chiral Imidazo[1,5-a]pyridine-Based Ligands for the Au-Catalyzed Enantioselective Intramolecular Hydrocarboxylation of Allenes
Chloé Stoll, Céline Besnard, Clément Mazet*
JACS Au 2025, 5, 4681-4687
91. A Simple yet Efficient Water-Saving Condenser
Stéphane Rosset, Clément Mazet*
ACS Omega 2025, 10, 34438-34441
90. Group XI Complexes Supported by Chiral N-Heterocyclic Ligands Built on the Imidazo[1,5-a]pyridin-3-ylidene Skeleton: Synthesis, Characterization, and Evaluation in Selective Catalysis
Chloé Stoll, Céline Besnard, Clément Mazet*
Organometallics 2025, 44, 952-958
89. Access to Enantioenriched 1,n-Diols by Cu-Catalyzed Enantioselective Protoboration and Hydroboration of Alkenyl Ethers
Arthur Flaget, Orlando Cesa, Clément Mazet*
Helv. Chim. Acta 2025, 108, e202500009
88. Enantioselective Synthesis of Pillar[5]arenes by Dynamic Kinetic Resolution via Pd-Catalyzed Suzuki Cross-Coupling
Antoine Konter, Jaume Rostoll-Berenguer, Céline Besnard, Baptiste Leforestier,* Clément Mazet*
ACS Catal. 2025, 15, 2607-2619
competing transition states visible here: favored vs. disfavored
87. Ni-Catalyzed Enantioconvergent Kumada–Corriu Cross-Coupling between β-Bromostyrenes and Secondary Grignard Reagents: Reaction Development, Scope and Mechanistic Investigations
Kaidi Li, Baptiste Leforestier, Amalia I. Poblador-Bahamonde, Céline Besnard, Laure Guénée, Svetlana Kucher, Clément Mazet*
ACS Catal. 2025, 15, 392-402
86. Stopper system for a waterless glass condenser and a water glass condenser system
Stéphane Rosset, Clément Mazet
European Patent Application 2024, EP24205965.7
85. Access to 1,2- and 1,3-Amino Alcohols via Cu-Catalyzed Enantioselective Borylations of Allylamines
Arthur Flaget, Clément Mazet*
Org. Lett. 2024, 26, 8542-8547
84. Ni-Catalyzed Kumada–Corriu Cross-Coupling Reactions of Tertiary Grignard Reagents and Bromostyrenes
Kaidi Li, Bing Zu, Clément Mazet*
Org. Lett. 2024, 26, 6047-6052
83. Remote Functionalization by Pd-Catalyzed Isomerization of Alkynyl Alcohols
Simone Scaringi, Baptiste Leforestier, Clément Mazet*
J. Am. Chem. Soc. 2024, 146, 18606-18615
82. Access to Cyclic Borates by Cu-Catalyzed Borylation of Unactivated Vinylcyclopropanes
Cheng Zhang, Clément Mazet*
Org. Lett. 2024, 26, 5386-5390
81. Cu-Catalyzed Enantioselective Protoboration of 2,3-Disubstituted 1,3-Dienes
Sensheng Liu, Yangbin Liu, Arthur Flaget, Cheng Zhang, Clément Mazet*
Org. Lett. 2023, 25, 6897-6901
80. Pd-Catalyzed Regioselective Cyclopropanation of 2-Substituted 1,3-Dienes
Agonist Kastrati, Vincent Jaquier, Michele Garbo, Céline Besnard, Clément Mazet*
ACS Org. Inorg. Au 2023, 3, 291-298
79. Assisted Tandem Pd Catalysis Enables Regiodivergent Heck Arylation of Transiently Generated Substituted Enol Ethers
Thomas Duhamel, Simone Scaringi, Baptiste Leforestier, Amalia I. Poblador-Bahamonde, Clément Mazet*
JACS Au 2023, 3, 261-274
78. Ni-Catalyzed Enantioselective Hydrofunctionalizations of 1,3-Dienes
Arthur Flaget, Cheng Zhang, Clément Mazet*
ACS Catal. 2022, 12, 15638-15647
77. Transition metal-catalyzed (remote) deconjugative isomerization of α,β-unsaturated carbonyls
Simone Scaringi, Clément Mazet*
Tetrahedron Lett. 2022, 96, 153756-153742
76. Stereoselective Access to Conjugated and Cross-Conjugated Dienoates by Rh- and Ru-Catalyzed Isomerizations of Vinylcyclopropanes
Michele Garbo, Clément Mazet*
Org. Lett. 2022, 24, 752-756
75. Nickel-Catalyzed Kumada Vinylation of Enol Phosphates: A Comparative Mechanistic Study
Philippe-Alexandre Poisson, Gaël Tran, Céline Besnard, Clément Mazet*
ACS Catal. 2021, 11, 15041-15050
74. Teflon Magnetic Stirring Capsules (TMSC) as a Practical and Reusable Delivery System for Sensitive Reagents and Catalysts
Sylvain Taillemaud, Stéphane Rosset, Clément Mazet*
Helv. Chim. Acta 2021, 104, e2100110
73. Access to Highly Stereodefined 1,4-cis-Polydienes by a [Ni/Mg] Orthogonal Tandem Catalytic Polymerization
Daniele Fiorito, Malaury Simon, Christophe M. Thomas,* Clément Mazet*
J. Am. Chem. Soc. 2021, 143, 13401-13407
72. Kinetically Controlled Stereoselective Access to Branched 1,3-Dienes by Ru-Catalyzed Remote Conjugative Isomerization
Simone Scaringi, Clément Mazet*
ACS Catal. 2021, 11, 7970-7977
71. Bioinspired Ether Cyclizations within a π-Basic Capsule Compared to Autocatalysis on π-Acidic Surfaces and Pnictogen-Bonding Catalysts
Xiaoyu Hao, Tian-Ren Li, Hao Chen, Andrea Gini, Xiang Zhang, Stéphane Rosset, Clément Mazet, Konrad Tiefenbacher,* Stefan Matile*
Chem. Eur. J. 2021, 27, 12215-12223
70. Transition metal-catalyzed alkene isomerization as an enabling technology in tandem, sequential and domino processes
Daniele Fiorito, Simone Scaringi, Clément Mazet*
Chem. Soc. Rev. 2021, 50, 1391-1406
69. Ni-Catalyzed Regiodivergent and Stereoselective Hydroalkylation of Acyclic Branched Dienes with Unstabilized C(sp3) Nucleophiles
Wen Shao, Céline Besnard, Laure Guénée, Clément Mazet*
J. Am. Chem. Soc. 2020, 142, 16486-16492
68. Access to Optically Active 7-Membered Rings by a 2-Step Synthetic Sequence: Cu-Catalyzed Stereoselective Cyclopropanation of Branched 1,3-Dienes/Rh-Catalyzed Stereoconvergent [5+2] Cycloaddition
Michele Garbo, Céline Besnard, Laure Guénée, Clément Mazet*
ACS Catal. 2020, 10, 9604-9611
67. [n]Dendralenes as a Platform for Selective Catalysis: Ligand-Controlled Cu-Catalyzed Chemo-, Regio-, and Enantioselective Borylations
Camille Desfeux, Céline Besnard, Clément Mazet*
Org. Lett. 2020, 22, 8181-8187
66. A Catalytic Dual Isomerization/Allylboration Sequence for the Stereoselective Construction of Congested Secondary Homoallylic Alcohols
Yangbin Liu, Clément Mazet*
J. Org. Chem. 2020, 85, 5638-5650
65. Direct Access to Chiral Secondary Amides by Copper-Catalyzed Borylative Carboxamidation of Vinylarenes with Isocyanates
Daniele Fiorito, Yangbin Liu, Céline Besnard, Clément Mazet*
J. Am. Chem. Soc. 2020, 142, 623-632
64. Ni-Catalyzed Regioselective Hydroalkoxylation of Branched 1,3-Dienes
Gaël Tran, Clément Mazet*
Org. Lett. 2019, 21, 9124-9127
63. Remote Functionalization of α,β-Unsaturated Carbonyls by Multimetallic Sequential Catalysis
Ciro Romano, Daniele Fiorito, Clément Mazet*
J. Am. Chem. Soc. 2019, 141, 16983-16990
62. Ni-Catalyzed Enantioselective Intermolecular Hydroamination of Branched 1,3-Dienes Using Primary Aliphatic Amines
Gaël Tran, Wen Shao, Clément Mazet*
J. Am. Chem. Soc. 2019, 141, 14814-14822
61. Editorial: Organometallics and Catalysis
Clément Mazet*
CHIMIA 2018, 72, 577
60. Ir-Catalyzed Selective Hydroboration of 2-Substituted 1,3-Dienes: A General Method to Access Homoallylic Boronates
Daniele Fiorito, Clément Mazet*
ACS Catal. 2018, 8, 9382-9387
59. Copper-Catalyzed Enantioselective 1,2-Borylation of 1,3-Dienes
Yangbin Liu, Daniele Fiorito, Clément Mazet*
Chem. Sci. 2018, 9, 5284-5288
58. Multicatalytic Stereoselective Synthesis of Highly Substituted Alkenes by Sequential Isomerization/Cross-Coupling Reactions
Ciro Romano, Clément Mazet*
J. Am. Chem. Soc. 2018, 140, 4743-4750
57. A General Nickel-Catalyzed Kumada Vinylation for the Preparation of 2-Substituted 1,3-Dienes
Daniele Fiorito, Sarah Folliet, Yangbin Liu, Clément Mazet*
ACS Catal. 2018, 8, 1392-1398
56. Mechanistic Investigation of the Pd-Catalyzed Intermolecular Carboetherification and Carboamination of 2,3-Dihydrofuran: Similarities, Differences, and Evidence for Unusual Reaction Intermediates
Gustavo M. Borrajo-Calleja, Vincent Bizet, Céline Besnard, Clément Mazet*
Organometallics 2017, 36, 3553-3563
55. Exploring Site Selectivity of Iridium Hydride Insertion into Allylic Alcohols: Serendipitous Discovery and Comparative Study of an Organic and an Organometallic Catalysts for the Vinylogous Peterson Elimination
Houhua Li, Daniele Fiorito, Clément Mazet*
ACS Catal. 2017, 7, 1554-1562
54. Influence of the Dissolution Solvent on the Cytotoxicity of Octahedral Cationic Ir(III) Hydride Complexes
Huaiyi Huang, Nicolas Humbert, Vincent Bizet, Malay Patra, Hui Chao,* Clément Mazet,* Gilles Gasser*
J. Organomet. Chem. 2017, 839, 15-18
53. Magnetic Stirring Capsules
Stéphane Rosset, Clément Mazet, Christophe Girard
International Patent Application 2017, WO/2017/216361
52. Direct Access to Furoindolines by Palladium-Catalyzed Intermolecular Carboamination
Vincent Bizet, Gustavo M. Borrajo-Calleja, Celine Besnard, Clément Mazet*
ACS Catal. 2016, 6, 7183-7187
51. The Diastereoselective Synthesis of Octahedral Cationic Iridium Hydride Complexes with a Stereogenic Metal Centre
Nicolas Humbert, Clément Mazet*
Chem. Commun. 2016, 52, 10629-10631
50. Palladium-Catalyzed Long-Range Deconjugative Isomerization of Highly Substituted α,β-Unsaturated Carbonyl Compounds
Luqing Lin, Ciro Romano, Clément Mazet*
J. Am. Chem. Soc. 2016, 138, 10344-10350
49. Iridium-Catalyzed Selective Isomerization of Primary Allylic Alcohols
Houhua Li, Clément Mazet*
Acc. Chem. Res. 2016, 49, 1232-1241
48. Palladium-Catalyzed Enantioselective Intermolecular Carboetherification of Dihydrofurans
Gustavo M. Borrajo Calleja, Vincent Bizet, Clément Mazet*
J. Am. Chem. Soc. 2016, 138, 4014-4017 
47. Organometallic Complexes of Iridium (Update 2015)
Houhua Li, Clément Mazet*
in SOS Science of Synthesis; R. Alan Aitken, Mogens Brønsted Nielsen, Jozef Drabowicz, Jie Jack Li, Bernd J. Plietker, Thomas Wirth (Eds.)Thieme: Stuttgart - New York, 2016; Knowledge Updates 2015/2; p. 21-58
46. Pd2Au36(SR)24 cluster: structure studies
Bei Zhang, Sameh Kaziz, Houhua Li, Dawid Wodka, Sami Malola, Olga V. Safonova, Maarten Nachtegaal, Clément Mazet, Igor Dolamic, Jordi Llorca, Elina Kalenius, Latévi Max Lawson Daku, Hannu Häkkinen, Thomas Bürgi,* Noelia Barrabés*
Nanoscale 2015, 7, 17012-17019
45. Catalyst-Directed Diastereoselective Isomerization of Allylic Alcohols for the Stereoselective Construction of C(20) in Steroid Side Chains: Scope and Topological Diversification
Houhua Li, Clément Mazet*
J. Am. Chem. Soc. 2015, 137, 10720-10727 
44. Access to Enantioenriched 2,3- and 2,5-Dihydrofurans with a Fully Substituted C2 Stereocenter by Pd-Catalyzed Asymmetric Intermolecular Heck Reaction
Gustavo M. Borrajo Calleja, Vincent Bizet, Thomas Bürgi, Clément Mazet*
Chem. Sci. 2015, 6, 4807-4811 
43. A general Pd-catalyzed α− and γ−benzylation of aldehydes for the formation of quaternary centers
Ivan Franzoni, Laure Guénée, Clément Mazet*
Org. Biomol. Chem. 2015, 13, 6338-6343
42. Modulation of Active Sites in Supported Au38(SC2H4Ph)24 Cluster Catalysts: Effect of Atmosphere and Support Material
Bei Zhang, Sameh Kaziz, Houhua Li, Miguel González Hevia, Dawid Wodka, Clément Mazet, Thomas Bürgi,* Noelia Barrabés*
J. Phys. Chem. C 2015, 119, 11193-11199
41. Scope and Mechanism in Palladium-Catalyzed Isomerizations of Highly Substituted Allylic, Homoallylic and Alkenyl Alcohols
Evgeny Larionov, Luqing Lin, Laure Guénée, Clément Mazet*
J. Am. Chem. Soc. 2014, 136, 16882-16894
40. An Air-stable Cationic Iridium Hydride as a Highly Active and General Catalyst for the Isomerization of Terminal Epoxides
Nicolas Humbert, Devendra J. Vyas, Céline Besnard, Clément Mazet*
Chem. Commun. 2014, 50, 10592-10595
39. Well-defined Transition Metal Hydrides in Catalytic Isomerizations
Evgeny Larionov, Houhua Li, Clément Mazet*
Chem. Commun. 2014, 50, 9816-9826
38. Chiral Monodentate Phosphine Ligands for the Enantioselective α− and γ−arylation of Aldehydes
Ivan Franzoni, Laure Guénée, Clément Mazet*
Tetrahedron 2014, 70, 4181-4190
[ Dedicated to Prof. Sarah Reisman on receipt of the Tetrahedron Young Investigator Award 2014 ]
37. Highly Modular C1-Symmetric Chiral (P,N) Ligands with a Stereolabile P Center: Experimental and Theoretical Studies
Nicolas Humbert, Evgeny Larionov, Luca Mantilli, Pradeep Nareddy, Céline Besnard, Laure Guénée, Clément Mazet*
Chem. Eur. J. 2014, 20, 745-751
36. Recent Trends in Pd-catalyzed Remote Functionalization of Carbonyl Compounds
Ivan Franzoni, Clément Mazet*
Org. Biomol. Chem. 2014, 12, 233-241
35. Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols
Houhua Li, Clément Mazet*
Org. Lett. 2013, 15, 6170-6173
34. Complementary Catalytic Strategies to Access α-Chiral Aldehydes
Clément Mazet*
CHIMIA 2013, 67, 658-662
33. α-Arylation, α-Arylative Esterification, or Acylation: A Stoichiometry-Dependent Trichotomy in the Pd-Catalyzed Cross-Coupling between Aldehydes and Aryl Bromides
Pradeep Nareddy, Clément Mazet*
Chem. Asian J. 2013, 8, 2579-2583
32. Access to Congested Quaternary Centers by Pd-catalyzed Intermolecular γ-arylation of Unactivated α,β-unsaturated Aldehydes
Ivan Franzoni, Laure Guénée, Clément Mazet*
Chem. Sci. 2013, 4, 2619-2624
31. Isomerization of Terminal Epoxides by a [Pd-H] Catalyst: A Combined Experimental and Theoretical Mechanistic Study
Devendra J. Vyas, Evgeny Larionov, Céline Besnard, Laure Guénée, Clément Mazet*
J. Am. Chem. Soc. 2013, 135, 6177-6183
30. Challenges and Achievements in the Transition Metal-catalyzed Asymmetric α-Arylation of Aldehydes
Clément Mazet*
Synlett 2012, 23, 1999-2004
29. Structure-Activity Relationship in the Iridium-Catalyzed Isomerization of Primary Allylic Alcohols
Luca Mantilli, David Gérard, Céline Besnard, Clément Mazet*
Eur. J. Inorg. Chem. 2012, 20, 3320-3330
28. Atropoisomeric (P,N) Ligands for the Highly Enantioselective Pd-Catalyzed Intramolecular Asymmetric α-Arylation of α-Branched Aldehydes
Pradeep Nareddy, Luca Mantilli, Laure Guénée, Clément Mazet*
Angew. Chem. Int. Ed. 2012, 51, 3826-3831
27. Privileged Chiral Ligands and Catalysts (book review)
Clément Mazet*
Angew. Chem. Int. Ed. 2012, 51, 305
26. New Catalytic Asymmetric Strategies to Access Chiral Aldehydes
Clément Mazet*
CHIMIA 2011, 65, 802-805
25. Platinum Metals in the Asymmetric Isomerization of Allylic Alcohols
Luca Mantilli, Clément Mazet*
Chem. Lett. 2011, 40, 341-344
24. Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis
Adrien Quintard, Alexandre Alexakis,* Clément Mazet*
Angew. Chem. Int. Ed. 2011, 50, 2354-2358 
23. Highly Regio- and Enantioselective Catalytic Asymmetric Hydroboration of α-Substituted Styrenyl Derivatives
Clément Mazet,* David Gérard
Chem. Commun. 2011, 47, 298-300 
22. Improved Catalysts for the Iridium-catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Based on Charton Analysis
Luca Mantilli, David Gérard, Sonya Torche, Céline Besnard, Clément Mazet*
Chem. Eur. J. 2010, 16, 12736-12745
21. The 3rd Young Faculty Meeting – Looking Back at the Past to Better Anticipate the Future
Barbara Winter-Werner,* Clément Mazet*
CHIMIA 2010, 64, 621-622
20. The 45th EUCHEM Conference on Stereochemistry (Bürgenstock Conference 2010)
Clément Mazet,* Cristina Nevado*
CHIMIA 2010, 64, 421-424
19. Highly Enantioselective Isomerization of Primary Allylic Alcohols Catalyzed by (P,N)-iridium complexes
Luca Mantilli, David Gérard, Sonya Torche, Céline Besnard, Clément Mazet*
Pure Appl. Chem. 2010, 82, 1461-1469
18. Copper-Catalyzed Asymmetric β-Boration of α,β-Unsaturated Carbonyl Derivatives
Luca Mantilli, Clément Mazet*
ChemCatChem 2010, 2, 501-504
17. Expanded Scope for the Iridium-catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Using Readily Accessible Second-generation Catalysts
Luca Mantilli, Clément Mazet*
Chem. Commun. 2010, 46, 445-447
16. Organic Chemistry à la Genevoise
Clément Mazet, Andreas Zumbuehl, Damien Jeannerat, Jiri Mareda, Alexandre Alexakis, E. Peter Kündig, Jérôme Lacour, Stefan Matile
CHIMIA 2009, 63, 816-821
15. Iridium-catalyzed Asymmetric Isomerization of Primary Allylic Alcohols
Luca Mantilli, David Gérard, Sonya Torche, Céline Besnard, Clément Mazet*
Angew. Chem. Int. Ed. 2009, 48, 5143-5147 
14. Iridium-catalyzed Isomerization of Primary Allylic Alcohols Under Mild Reaction Conditions
Luca Mantilli, Clément Mazet*
Tetrahedron Lett. 2009, 50, 4141-4144 [ Supporting Information ]
13. Iridium-catalyzed Isomerization of Primary Allylic Alcohols
Luca Mantilli, Clément Mazet*
CHIMIA 2009, 63, 35-37
Before University of Geneva
12. Chiral Boron-Bridged Bisoxazoline (Borabox) Ligands: Structures and Reactivities of Pd and Cu Complexes
Valentin Köhler, Clément Mazet, Aurélie Toussaint, Klaus Kulicke, Daniel Häussinger, Markus Neuburger, Silvia Schaffner, Stefan Kaiser, Andreas Pfaltz*
Chem. Eur. J. 2008, 14, 8530-8539
11. Dinuclear {(salen)Al} Complexes Display Expanded Scope in the Conjugate Cyanation of α,β-Unsaturated Imides
Clément Mazet, Eric N. Jacobsen*
Angew. Chem. Int. Ed. 2008, 47, 1762-1765
10. Kinetic Resolution of Diols and Pyridyl Alcohols by Cu(II)(borabox)-Catalyzed Acylation
Clément Mazet, Stephen Roseblade, Valentin Köhler, Andreas Pfaltz*
Org. Lett. 2006, 8, 1879-1882
9. Synthesis of Chiral Boron-bridged Anionic C2-symmetric Bisoxazolines and their Applications in Asymmetric Catalysis
Clément Mazet,* Valentin Köhler, Stephen Roseblade, Aurélie Toussaint, Andreas Pfaltz*
CHIMIA 2006, 60, 195-198
8. Chiral Boron-Bridged Bisoxazolines: Readily Available Anionic Ligands for Asymmetric Catalysis
Clément Mazet, Valentin Köhler, Andreas Pfaltz*
Angew. Chem. Int. Ed. 2005, 44, 4888-4891
7. A Combined Experimental and Computational Study of Dihydrido-Phosphinooxazoline Iridium Complexes
Clément Mazet, Sebastian P. Smidt, Markus Meuwly,* Andreas Pfaltz*
J. Am. Chem. Soc. 2004, 126, 14176-14181
6. Synthesis and Coordination Chemistry of the First C2-Chiral Bisoxazine Ligand
Clément Mazet, Lutz H. Gade*
Inorg. Chem. 2003, 42, 210-215
5. [Bis(oxazolinyl)pyrrole]palladium Complexes as Catalysts in Heck- and Suzuki-Type C-C Coupling Reactions
Clément Mazet, Lutz H. Gade*
Eur. J. Inorg. Chem. 2003, 1161-1168
4. Double Bonds in Motion: Bis(oxazolinylmethyl)pyrroles and Their Metal-Induced Planarization to a New Class of Rigid Chiral C2-symmetric Complexes
Clément Mazet, Lutz H. Gade*
Chem. Eur. J. 2003, 9, 1759-1767
3. Charging and Deforming the Pybox Ligand: Enantiomerically Pure Double Helices and Their Interconversion
Clément Mazet, Lutz H. Gade*
Chem. Eur. J. 2002, 8, 4308-4318
2. Solution Structure and Decomposition Pathway of Zwitterionic Zirconium(IV) Benzyl Complexes
Régis M. Gauvin, Clément Mazet, Jacky Kress*
J. Organomet. Chem. 2002, 658, 1-8
1. A Bis(oxazolinyl)pyrrole as a New Monoanionic Tridentate Supporting Ligand: Synthesis of a Highly Active Palladium Catalyst for Suzuki-Type C-C Coupling
Clément Mazet, Lutz H. Gade*
Organometallics 2001, 20, 4144-4146