Organic-Rich volatile worlds: linking stellar composition, thermochemical evolution, and atmospheric signatures
Mathilde Kervazo,Nantes University
Seminar
Rue des Maraîchers 13, Room 001
Organic ma*er is expected to be a key component of bodies formed in the outer regions of planetary systems. In the Solar System, measured moments of iner=a, interpreted with equa=ons of state for ices, silicates, and carbonaceous materials, suggest that organics may cons=tute a major frac=on of the refractory interiors of several icy bodies (e.g., Reynard & So=n, 2023; Delarue et al., 2026). Organics may therefore exert a first-order control on thermochemical evolu=on and vola=le produc=on—an idea that is par=cularly =mely given the growing popula=on of low-density exoplanets. The presenta=on will summarize recent work aiming at (i) predic=ng the occurrence of organic-rich vola=le worlds from host-star elemental abundances, and (ii) quan=fying the impact of carbon/organics on thermochemical evolu=on. On the occurrence side, stellar abundance pa*erns are used to iden=fy systems in which the available refractory and vola=le budgets favor carbonrich/organic-rich condensates beyond the relevant condensa=on fronts. On the interior side, evolu=on is modeled by combining equa=ons of state for ices, silicates and carbonaceous materials with kine=c descrip=ons of the transforma=on of a representa=ve organic compound as a func=on of =me and temperature. The kine=c scheme tracks the progressive loss of H and heteroatoms from the carbonaceous phase, the associated increase in residual carbon density toward graphite-like values, and the produc=on of mobile vola=les. These processes feed back on the thermal history and set the =me-dependent inventories of poten=ally releasable species. Model outputs are used to quan=fy expected vola=le release for Titan-like bodies and carbon-rich exoplanets, and to contrast these outcomes with classical telluric and ice–silicate evolu=on pathways. Implica=ons for JWST-era characteriza=on of low-density planets, and for joint constraints from mass–radius measurements, stellar abundances, and interior evolu=on models, are discussed.